Zirconocene catalyzed diastereoselective carbometalation of cyclobutenes

Sudipta Raha Roy; Hendrik Eijsberg; Jeffrey Bruffaerts; Ilan Marek

doi:10.1039/c6sc02617f

Zirconocene catalyzed diastereoselective carbometalation of cyclobutenes

Sudipta Raha Roy, Hendrik Eijsberg, Jeffrey Bruffaerts, Ilan Marek

Technion - Israel Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

The regio- and diastereoselective zirconocene-catalyzed carbomagnesiation of cyclobutenes is herein reported to afford configurationally stable cyclobutylmagnesium species that could subsequently react with a large variety of electrophiles to give polysubstituted cyclobutane species as a single diastereoisomer.

Original language	English
Pages (from-to)	334-339
Number of pages	6
Journal	Chemical Science
Volume	8
Issue number	1
DOIs	https://doi.org/10.1039/c6sc02617f
State	Published - 1 Jan 2017

All Science Journal Classification (ASJC) codes

General Chemistry

Access to Document

10.1039/c6sc02617f

Cite this

@article{9b5b9a2ad8384df29d8151b2be0cdeec,

title = "Zirconocene catalyzed diastereoselective carbometalation of cyclobutenes",

abstract = "The regio- and diastereoselective zirconocene-catalyzed carbomagnesiation of cyclobutenes is herein reported to afford configurationally stable cyclobutylmagnesium species that could subsequently react with a large variety of electrophiles to give polysubstituted cyclobutane species as a single diastereoisomer.",

author = "Roy, \{Sudipta Raha\} and Hendrik Eijsberg and Jeffrey Bruffaerts and Ilan Marek",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry",

year = "2017",

month = jan,

day = "1",

doi = "10.1039/c6sc02617f",

language = "الإنجليزيّة",

volume = "8",

pages = "334--339",

journal = "Chemical Science",

issn = "2041-6520",

publisher = "Royal Society of Chemistry",

number = "1",

}

TY - JOUR

T1 - Zirconocene catalyzed diastereoselective carbometalation of cyclobutenes

AU - Roy, Sudipta Raha

AU - Eijsberg, Hendrik

AU - Bruffaerts, Jeffrey

AU - Marek, Ilan

PY - 2017/1/1

Y1 - 2017/1/1

N2 - The regio- and diastereoselective zirconocene-catalyzed carbomagnesiation of cyclobutenes is herein reported to afford configurationally stable cyclobutylmagnesium species that could subsequently react with a large variety of electrophiles to give polysubstituted cyclobutane species as a single diastereoisomer.

AB - The regio- and diastereoselective zirconocene-catalyzed carbomagnesiation of cyclobutenes is herein reported to afford configurationally stable cyclobutylmagnesium species that could subsequently react with a large variety of electrophiles to give polysubstituted cyclobutane species as a single diastereoisomer.

UR - http://www.scopus.com/inward/record.url?scp=85007157640&partnerID=8YFLogxK

U2 - 10.1039/c6sc02617f

DO - 10.1039/c6sc02617f

M3 - مقالة

SN - 2041-6520

VL - 8

SP - 334

EP - 339

JO - Chemical Science

JF - Chemical Science

IS - 1

ER -

Zirconocene catalyzed diastereoselective carbometalation of cyclobutenes

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this