VLE property measurements and PC-SAFT/ CP- PC-SAFT/ E-PPR78 modeling of the CO2 + n-tetradecane mixture

Vener F. Khairutdinov; Farid M. Gumerov; Ilnar Sh Khabriev; Talgat R. Akhmetzyanov; Ilfat Z. Salikhov; Ilya Polishuk; Ilmutdin M. Abdulagatov

doi:10.1016/j.fluid.2022.113615

VLE property measurements and PC-SAFT/ CP- PC-SAFT/ E-PPR78 modeling of the CO₂ + n-tetradecane mixture

Vener F. Khairutdinov, Farid M. Gumerov, Ilnar Sh Khabriev, Talgat R. Akhmetzyanov, Ilfat Z. Salikhov, Ilya Polishuk, Ilmutdin M. Abdulagatov

Department of Chemical Engineering

Ariel University

Research output: Contribution to journal › Article › peer-review

Abstract

This paper presents a new experimental VLE property data in the binary system of carbon dioxide – n-tetradecane at three selected isotherms of 313.15 K, 333.15 K, and 353.15 K in the pressure range from (3.8 to 19.0) MPa. The measurements were made using a high-temperature and high-pressure optical cell. The standard absolute u and relativeu_r uncertainties of temperature, pressure, concentration measurements are: u(T)=7.5 mK; u_r(P)=0.00025; u_r(x)=0.015; and u_r(y)=0.015. The measured VLE data were used to determine the criticalP_C-T_C curve data. Based on the derived values of the critical parameters of CO₂+n-tetradecane mixture the value (-67.58 MPa) of the Krichevskii parameter has been determined. The predictive capabilities of the perturbed chain-statistical associating fluid theory (PC-SAFT), the critical point-based modification of PC-SAFT (CP-PC-SAFT), and the Enhanced-Predictive-Peng-Robinson-78 (E-PPR78) models were examined.

Original language	English
Article number	113615
Journal	Fluid Phase Equilibria
Volume	564
DOIs	https://doi.org/10.1016/j.fluid.2022.113615
State	Published - Jan 2023

Keywords

CO+n-tetradecane mixture
Critical curve
Equation of state
Krichevskii parameter
Phase diagram
Supercritical solvent
VLE measurements

All Science Journal Classification (ASJC) codes

General Chemical Engineering
General Physics and Astronomy
Physical and Theoretical Chemistry

Access to Document

10.1016/j.fluid.2022.113615

Cite this

@article{0e508ae037b840c2b2398936f8b379e2,

title = "VLE property measurements and PC-SAFT/ CP- PC-SAFT/ E-PPR78 modeling of the CO2 + n-tetradecane mixture",

abstract = "This paper presents a new experimental VLE property data in the binary system of carbon dioxide – n-tetradecane at three selected isotherms of 313.15 K, 333.15 K, and 353.15 K in the pressure range from (3.8 to 19.0) MPa. The measurements were made using a high-temperature and high-pressure optical cell. The standard absolute u and relativeur uncertainties of temperature, pressure, concentration measurements are: u(T)=7.5 mK; ur(P)=0.00025; ur(x)=0.015; and ur(y)=0.015. The measured VLE data were used to determine the criticalPC-TC curve data. Based on the derived values of the critical parameters of CO2+n-tetradecane mixture the value (-67.58 MPa) of the Krichevskii parameter has been determined. The predictive capabilities of the perturbed chain-statistical associating fluid theory (PC-SAFT), the critical point-based modification of PC-SAFT (CP-PC-SAFT), and the Enhanced-Predictive-Peng-Robinson-78 (E-PPR78) models were examined.",

keywords = "CO+n-tetradecane mixture, Critical curve, Equation of state, Krichevskii parameter, Phase diagram, Supercritical solvent, VLE measurements",

author = "Khairutdinov, \{Vener F.\} and Gumerov, \{Farid M.\} and Khabriev, \{Ilnar Sh\} and Akhmetzyanov, \{Talgat R.\} and Salikhov, \{Ilfat Z.\} and Ilya Polishuk and Abdulagatov, \{Ilmutdin M.\}",

note = "Publisher Copyright: {\textcopyright} 2022",

year = "2023",

month = jan,

doi = "10.1016/j.fluid.2022.113615",

language = "الإنجليزيّة",

volume = "564",

journal = "Fluid Phase Equilibria",

issn = "0378-3812",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - VLE property measurements and PC-SAFT/ CP- PC-SAFT/ E-PPR78 modeling of the CO2 + n-tetradecane mixture

AU - Khairutdinov, Vener F.

AU - Gumerov, Farid M.

AU - Khabriev, Ilnar Sh

AU - Akhmetzyanov, Talgat R.

AU - Salikhov, Ilfat Z.

AU - Polishuk, Ilya

AU - Abdulagatov, Ilmutdin M.

PY - 2023/1

Y1 - 2023/1

N2 - This paper presents a new experimental VLE property data in the binary system of carbon dioxide – n-tetradecane at three selected isotherms of 313.15 K, 333.15 K, and 353.15 K in the pressure range from (3.8 to 19.0) MPa. The measurements were made using a high-temperature and high-pressure optical cell. The standard absolute u and relativeur uncertainties of temperature, pressure, concentration measurements are: u(T)=7.5 mK; ur(P)=0.00025; ur(x)=0.015; and ur(y)=0.015. The measured VLE data were used to determine the criticalPC-TC curve data. Based on the derived values of the critical parameters of CO2+n-tetradecane mixture the value (-67.58 MPa) of the Krichevskii parameter has been determined. The predictive capabilities of the perturbed chain-statistical associating fluid theory (PC-SAFT), the critical point-based modification of PC-SAFT (CP-PC-SAFT), and the Enhanced-Predictive-Peng-Robinson-78 (E-PPR78) models were examined.

AB - This paper presents a new experimental VLE property data in the binary system of carbon dioxide – n-tetradecane at three selected isotherms of 313.15 K, 333.15 K, and 353.15 K in the pressure range from (3.8 to 19.0) MPa. The measurements were made using a high-temperature and high-pressure optical cell. The standard absolute u and relativeur uncertainties of temperature, pressure, concentration measurements are: u(T)=7.5 mK; ur(P)=0.00025; ur(x)=0.015; and ur(y)=0.015. The measured VLE data were used to determine the criticalPC-TC curve data. Based on the derived values of the critical parameters of CO2+n-tetradecane mixture the value (-67.58 MPa) of the Krichevskii parameter has been determined. The predictive capabilities of the perturbed chain-statistical associating fluid theory (PC-SAFT), the critical point-based modification of PC-SAFT (CP-PC-SAFT), and the Enhanced-Predictive-Peng-Robinson-78 (E-PPR78) models were examined.

KW - CO+n-tetradecane mixture

KW - Critical curve

KW - Equation of state

KW - Krichevskii parameter

KW - Phase diagram

KW - Supercritical solvent

KW - VLE measurements

UR - http://www.scopus.com/inward/record.url?scp=85138450169&partnerID=8YFLogxK

U2 - 10.1016/j.fluid.2022.113615

DO - 10.1016/j.fluid.2022.113615

M3 - مقالة

SN - 0378-3812

VL - 564

JO - Fluid Phase Equilibria

JF - Fluid Phase Equilibria

M1 - 113615

ER -