Utilizing Phase Separation Reactions for Enhancement of the Thermoelectric Efficiency in IV-VI Alloys

Research output: Chapter in Book/Report/Conference proceedingChapterpeer-review

Abstract

The current chapter reviews the principles and methods for exploiting thermodynamically driven phase separation effects such as nucleation and growth and spinodal decomposition for enhancing the thermoelectric figure of merit through bulk nanostructuring of selected IV-VI systems. Special emphasis is laid on the p-type (GeTe)0.87(PbTe)0.13 and the n-type (Pb0.95Sn0.05Te)0.92(PbS)0.08, exhibiting very high maximal ZTs of 2.2 and 1.5, respectively.

Original languageAmerican English
Title of host publicationThermoelectric Energy Conversion
Subtitle of host publicationBasic Concepts and Device Applications
Pages1-14
Number of pages14
ISBN (Electronic)9783527698110
DOIs
StatePublished - 1 Jan 2017

Keywords

  • alloy
  • enthalpy
  • reaction
  • thermoelectric

All Science Journal Classification (ASJC) codes

  • General Engineering
  • General Materials Science

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