Understanding the distribution of chlorine in perovskite solar cells via x-ray fluorescence microscopyl

Yanqi Luo; Shany Gamliel; Sally Nijem; Sigalit Aharon; Martin Holt; Benjamin Stripe; Volker Rose; Mariana I. Bertoni; Lioz Etgar; David P. Fenning

doi:10.1109/PVSC.2016.7749715

Understanding the distribution of chlorine in perovskite solar cells via x-ray fluorescence microscopyl

Yanqi Luo, Shany Gamliel, Sally Nijem, Sigalit Aharon, Martin Holt, Benjamin Stripe, Volker Rose, Mariana I. Bertoni, Lioz Etgar, David P. Fenning

Institute of Chemistry

The Hebrew University of Jerusalem

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

Spatial heterogeneities in the chemical makeup of thin film photovoltaic devices are pivotal in determining device efficiency. In this study, the presence of chlorine is identified in perovskite films synthesized with Cl-containing precursors by means of nanoprobe X-ray fluorescence (Nano-XRF). Additionally, a spatial variation in the Cl incorporation is observed within a given film, and the standard deviation of Cl: I ratio across the film is large. Using Nano-XRF, the Cl incorporation in methylammonium lead iodide perovskite films can be manipulated by precursor stoichiometry ratio.

Original language	English
Title of host publication	2016 IEEE 43rd Photovoltaic Specialists Conference, PVSC 2016
Publisher	Institute of Electrical and Electronics Engineers Inc.
Pages	802-803
Number of pages	2
ISBN (Electronic)	9781509027248
DOIs	https://doi.org/10.1109/PVSC.2016.7749715
State	Published - 18 Nov 2016
Event	43rd IEEE Photovoltaic Specialists Conference, PVSC 2016 - Portland, United States Duration: 5 Jun 2016 → 10 Jun 2016

Publication series

Name	Conference Record of the IEEE Photovoltaic Specialists Conference
Volume	2016-November

Conference

Conference	43rd IEEE Photovoltaic Specialists Conference, PVSC 2016
Country/Territory	United States
City	Portland
Period	5/06/16 → 10/06/16

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

Cl containing precursors
elemental distribution
nano-XRF
perovskite solar cells
synchrotron based technique

All Science Journal Classification (ASJC) codes

Control and Systems Engineering
Industrial and Manufacturing Engineering
Electrical and Electronic Engineering

Access to Document

10.1109/PVSC.2016.7749715

Cite this

Luo, Y., Gamliel, S., Nijem, S., Aharon, S., Holt, M., Stripe, B., Rose, V., Bertoni, M. I., Etgar, L., & Fenning, D. P. (2016). Understanding the distribution of chlorine in perovskite solar cells via x-ray fluorescence microscopyl. In 2016 IEEE 43rd Photovoltaic Specialists Conference, PVSC 2016 (pp. 802-803). Article 7749715 (Conference Record of the IEEE Photovoltaic Specialists Conference; Vol. 2016-November). Institute of Electrical and Electronics Engineers Inc.. https://doi.org/10.1109/PVSC.2016.7749715

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title = "Understanding the distribution of chlorine in perovskite solar cells via x-ray fluorescence microscopyl",

abstract = "Spatial heterogeneities in the chemical makeup of thin film photovoltaic devices are pivotal in determining device efficiency. In this study, the presence of chlorine is identified in perovskite films synthesized with Cl-containing precursors by means of nanoprobe X-ray fluorescence (Nano-XRF). Additionally, a spatial variation in the Cl incorporation is observed within a given film, and the standard deviation of Cl: I ratio across the film is large. Using Nano-XRF, the Cl incorporation in methylammonium lead iodide perovskite films can be manipulated by precursor stoichiometry ratio.",

keywords = "Cl containing precursors, elemental distribution, nano-XRF, perovskite solar cells, synchrotron based technique",

author = "Yanqi Luo and Shany Gamliel and Sally Nijem and Sigalit Aharon and Martin Holt and Benjamin Stripe and Volker Rose and Bertoni, \{Mariana I.\} and Lioz Etgar and Fenning, \{David P.\}",

note = "Publisher Copyright: {\textcopyright} 2016 IEEE.; 43rd IEEE Photovoltaic Specialists Conference, PVSC 2016 ; Conference date: 05-06-2016 Through 10-06-2016",

year = "2016",

month = nov,

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doi = "10.1109/PVSC.2016.7749715",

language = "الإنجليزيّة",

series = "Conference Record of the IEEE Photovoltaic Specialists Conference",

publisher = "Institute of Electrical and Electronics Engineers Inc.",

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booktitle = "2016 IEEE 43rd Photovoltaic Specialists Conference, PVSC 2016",

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Luo, Y, Gamliel, S, Nijem, S, Aharon, S, Holt, M, Stripe, B, Rose, V, Bertoni, MI, Etgar, L & Fenning, DP 2016, Understanding the distribution of chlorine in perovskite solar cells via x-ray fluorescence microscopyl. in 2016 IEEE 43rd Photovoltaic Specialists Conference, PVSC 2016., 7749715, Conference Record of the IEEE Photovoltaic Specialists Conference, vol. 2016-November, Institute of Electrical and Electronics Engineers Inc., pp. 802-803, 43rd IEEE Photovoltaic Specialists Conference, PVSC 2016, Portland, United States, 5/06/16. https://doi.org/10.1109/PVSC.2016.7749715

Understanding the distribution of chlorine in perovskite solar cells via x-ray fluorescence microscopyl. / Luo, Yanqi; Gamliel, Shany; Nijem, Sally et al.
2016 IEEE 43rd Photovoltaic Specialists Conference, PVSC 2016. Institute of Electrical and Electronics Engineers Inc., 2016. p. 802-803 7749715 (Conference Record of the IEEE Photovoltaic Specialists Conference; Vol. 2016-November).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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AU - Luo, Yanqi

AU - Gamliel, Shany

AU - Nijem, Sally

AU - Aharon, Sigalit

AU - Holt, Martin

AU - Stripe, Benjamin

AU - Rose, Volker

AU - Bertoni, Mariana I.

AU - Etgar, Lioz

AU - Fenning, David P.

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N2 - Spatial heterogeneities in the chemical makeup of thin film photovoltaic devices are pivotal in determining device efficiency. In this study, the presence of chlorine is identified in perovskite films synthesized with Cl-containing precursors by means of nanoprobe X-ray fluorescence (Nano-XRF). Additionally, a spatial variation in the Cl incorporation is observed within a given film, and the standard deviation of Cl: I ratio across the film is large. Using Nano-XRF, the Cl incorporation in methylammonium lead iodide perovskite films can be manipulated by precursor stoichiometry ratio.

AB - Spatial heterogeneities in the chemical makeup of thin film photovoltaic devices are pivotal in determining device efficiency. In this study, the presence of chlorine is identified in perovskite films synthesized with Cl-containing precursors by means of nanoprobe X-ray fluorescence (Nano-XRF). Additionally, a spatial variation in the Cl incorporation is observed within a given film, and the standard deviation of Cl: I ratio across the film is large. Using Nano-XRF, the Cl incorporation in methylammonium lead iodide perovskite films can be manipulated by precursor stoichiometry ratio.

KW - Cl containing precursors

KW - elemental distribution

KW - nano-XRF

KW - perovskite solar cells

KW - synchrotron based technique

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PB - Institute of Electrical and Electronics Engineers Inc.

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ER -

Luo Y, Gamliel S, Nijem S, Aharon S, Holt M, Stripe B et al. Understanding the distribution of chlorine in perovskite solar cells via x-ray fluorescence microscopyl. In 2016 IEEE 43rd Photovoltaic Specialists Conference, PVSC 2016. Institute of Electrical and Electronics Engineers Inc. 2016. p. 802-803. 7749715. (Conference Record of the IEEE Photovoltaic Specialists Conference). doi: 10.1109/PVSC.2016.7749715

Understanding the distribution of chlorine in perovskite solar cells via x-ray fluorescence microscopyl

Abstract

Publication series

Conference

UN SDGs

Keywords

All Science Journal Classification (ASJC) codes

Access to Document

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