Transformation of π-conjugated macrocycles: from furanophanes to napthalenophanes

Shinaj K. Rajagopal; Or Dishi; Benny Bogoslavsky; Ori Gidron

doi:https://doi.org/10.1039/d2cc05434e

Transformation of π-conjugated macrocycles: from furanophanes to napthalenophanes

Shinaj K. Rajagopal, Or Dishi, Benny Bogoslavsky, Ori Gidron

Institute of Chemistry

The Hebrew University of Jerusalem

Research output: Contribution to journal › Article › peer-review

Abstract

Applying sequential Diels-Alder cycloaddition and deoxygenation to small π-conjugated furan macrocycles fully converts them to 1,4-naphthalophanes with either ethylene or acetylene spacers, depending on the reaction conditions. 1,4-Napthalenophane tetraene exhibits a 1,3-alternating conformation in the solid state, inclusion of solvent molecules within the macrocycle, and low reduction potentials.

Original language	English
Pages (from-to)	13652-13655
Number of pages	4
Journal	Chemical Communications
Volume	58
Issue number	98
DOIs	https://doi.org/10.1039/d2cc05434e
State	Published - 16 Nov 2022

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
General Chemistry
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Catalysis

Access to Document

https://doi.org/10.1039/d2cc05434e

Cite this

@article{bb5ace47d4294b3bbd799888ae282546,

title = "Transformation of π-conjugated macrocycles: from furanophanes to napthalenophanes",

abstract = "Applying sequential Diels-Alder cycloaddition and deoxygenation to small π-conjugated furan macrocycles fully converts them to 1,4-naphthalophanes with either ethylene or acetylene spacers, depending on the reaction conditions. 1,4-Napthalenophane tetraene exhibits a 1,3-alternating conformation in the solid state, inclusion of solvent molecules within the macrocycle, and low reduction potentials.",

author = "Rajagopal, {Shinaj K.} and Or Dishi and Benny Bogoslavsky and Ori Gidron",

note = "Publisher Copyright: {\textcopyright} 2022 The Royal Society of Chemistry.",

year = "2022",

month = nov,

day = "16",

doi = "https://doi.org/10.1039/d2cc05434e",

language = "الإنجليزيّة",

volume = "58",

pages = "13652--13655",

number = "98",

}

TY - JOUR

T1 - Transformation of π-conjugated macrocycles

T2 - from furanophanes to napthalenophanes

AU - Rajagopal, Shinaj K.

AU - Dishi, Or

AU - Bogoslavsky, Benny

AU - Gidron, Ori

PY - 2022/11/16

Y1 - 2022/11/16

N2 - Applying sequential Diels-Alder cycloaddition and deoxygenation to small π-conjugated furan macrocycles fully converts them to 1,4-naphthalophanes with either ethylene or acetylene spacers, depending on the reaction conditions. 1,4-Napthalenophane tetraene exhibits a 1,3-alternating conformation in the solid state, inclusion of solvent molecules within the macrocycle, and low reduction potentials.

AB - Applying sequential Diels-Alder cycloaddition and deoxygenation to small π-conjugated furan macrocycles fully converts them to 1,4-naphthalophanes with either ethylene or acetylene spacers, depending on the reaction conditions. 1,4-Napthalenophane tetraene exhibits a 1,3-alternating conformation in the solid state, inclusion of solvent molecules within the macrocycle, and low reduction potentials.

UR - http://www.scopus.com/inward/record.url?scp=85142751571&partnerID=8YFLogxK

U2 - https://doi.org/10.1039/d2cc05434e

DO - https://doi.org/10.1039/d2cc05434e

M3 - مقالة

C2 - 36412186

SN - 1359-7345

VL - 58

SP - 13652

EP - 13655

JO - Chemical Communications

JF - Chemical Communications

IS - 98

ER -

Transformation of π-conjugated macrocycles: from furanophanes to napthalenophanes

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this