Ti3C2Tz Supported Pulse-Electrodeposited Pt Nanostructures for Enhanced Acidic Electrochemical Hydrogen Evolution

Sukanta Chakrabartty, Haridas Parse, Mathias Krämer, Se Ho Kim, Dierk Raabe, Baptiste Gault, Maxim Sokol, Brian A. Rosen, Noam Eliaz

Research output: Contribution to journalArticlepeer-review

Abstract

Platinum (Pt)-based electrocatalysts are considered benchmark materials for the hydrogen evolution reaction (HER) in acidic solution. However, widespread use is limited by the high price of Pt. Tuning the Pt morphology to increase the catalytic surface area for the same mass loading is therefore essential to increase its utilization. Herein, single Ti3C2Tz flakes were deposited by electrophoresis onto a carbon-fiber gas diffusion layer, after which Pt nanostructures were selectively deposited onto the Ti3C2Tz flakes by pulse electrodeposition. It was observed that the pulse on-time (ton) and duration had a significant effect on the morphology and activity of the composite electrode towards HER. Flower-like and spherical morphologies were produced at long and short values of ton, respectively. As-synthesized electrocatalysts were studied for HER in 0.5 M sulfuric acid (H2SO4). The catalyst with the lowest Pt loading (10 μg/cm2), exhibited outstanding HER performance. It attained a current density of 10 mA/cm2 at an overpotential of 38 mV, close to that of commercial carbon supported platinum (Pt/C, Vulcan XC). This catalyst exhibited a high turnover frequency (23.9 H2 s−1 @ 100 mV), small Tafel slope (41 mV/dec), and high mass-specific activity (2.45 A/mgPt @ 100 mV).

Original languageEnglish
Article numbere202401088
JournalChemCatChem
Volume16
Issue number22
DOIs
StatePublished - 25 Nov 2024

Keywords

  • Electrophoresis
  • Hydrogen evolution reaction
  • Pt
  • Pulse-electrodeposition
  • Structure-activity
  • TiCT-MXene

All Science Journal Classification (ASJC) codes

  • Catalysis
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry
  • Organic Chemistry

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