The solubility limit of CaO in α-alumina at 1600°C

Ran Akiva; Alex Berner; Wayne D. Kaplan

doi:10.1111/jace.12442

The solubility limit of CaO in α-alumina at 1600°C

Ran Akiva, Alex Berner, Wayne D. Kaplan

Materials Science & Engineering

Technion - Israel Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

The solubility limit of Ca in 99.99% pure α-Al₂O ₃ (alumina) was measured using a wavelength dispersive spectrometer mounted on a scanning electron microscope. Al₂O₃ samples were equilibrated at a concentration which ensured saturation of the Al ₂O₃ grains with Ca, and were quenched in water from 1600°C. The results were compared with those from samples which were furnace cooled from 1600°C. For the quenched samples, the Ca solubility limit was found to be 51 ± 1 ppm, which is significantly larger than the solubility limit for samples which were furnace cooled (26 ± 1 ppm).

Original language	English
Pages (from-to)	3258-3264
Number of pages	7
Journal	Journal of the American Ceramic Society
Volume	96
Issue number	10
DOIs	https://doi.org/10.1111/jace.12442
State	Published - Oct 2013

All Science Journal Classification (ASJC) codes

Ceramics and Composites
Materials Chemistry

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10.1111/jace.12442

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title = "The solubility limit of CaO in α-alumina at 1600°C",

abstract = "The solubility limit of Ca in 99.99\% pure α-Al2O 3 (alumina) was measured using a wavelength dispersive spectrometer mounted on a scanning electron microscope. Al2O3 samples were equilibrated at a concentration which ensured saturation of the Al 2O3 grains with Ca, and were quenched in water from 1600°C. The results were compared with those from samples which were furnace cooled from 1600°C. For the quenched samples, the Ca solubility limit was found to be 51 ± 1 ppm, which is significantly larger than the solubility limit for samples which were furnace cooled (26 ± 1 ppm).",

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year = "2013",

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AU - Kaplan, Wayne D.

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N2 - The solubility limit of Ca in 99.99% pure α-Al2O 3 (alumina) was measured using a wavelength dispersive spectrometer mounted on a scanning electron microscope. Al2O3 samples were equilibrated at a concentration which ensured saturation of the Al 2O3 grains with Ca, and were quenched in water from 1600°C. The results were compared with those from samples which were furnace cooled from 1600°C. For the quenched samples, the Ca solubility limit was found to be 51 ± 1 ppm, which is significantly larger than the solubility limit for samples which were furnace cooled (26 ± 1 ppm).

AB - The solubility limit of Ca in 99.99% pure α-Al2O 3 (alumina) was measured using a wavelength dispersive spectrometer mounted on a scanning electron microscope. Al2O3 samples were equilibrated at a concentration which ensured saturation of the Al 2O3 grains with Ca, and were quenched in water from 1600°C. The results were compared with those from samples which were furnace cooled from 1600°C. For the quenched samples, the Ca solubility limit was found to be 51 ± 1 ppm, which is significantly larger than the solubility limit for samples which were furnace cooled (26 ± 1 ppm).

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M3 - مقالة

SN - 0002-7820

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JO - Journal of the American Ceramic Society

JF - Journal of the American Ceramic Society

IS - 10

ER -

The solubility limit of CaO in α-alumina at 1600°C

Abstract

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