The influence of chemical structure and the presence of ascorbic acid on anthocyanins stability and spectral properties in purified model systems

Rachel Levy, Zoya Okun, Avi Shpigelman

Research output: Contribution to journalArticlepeer-review

Abstract

The loss of color pigment is an important quality factor of food products. This work aimed to systematically study, in purified model systems, the influence of anthocyanins' structure (by increasing the size of the conjugated sugar) and the presence of ascorbic acid on their stability and spectral properties during storage at two pH levels relevant to medium and high acid foods (6.5 and 4.5, respectively). Anthocyanins (cyanidin (Cy), cyanidin 3-O-glucoside (Cy3G) and cyanidin 3-O-rutinoside (Cy3R)) displayed first-order degradation rates, presenting higher stability in acidic medium and enhanced stability with increasing size of conjugated sugar. The addition of ascorbic acid resulted in significantly enhanced degradation. Changes in ultra violet visible (UV-VIS) spectral properties presented a decrease in typical color intensity and pointed towards formation of degradation products. Identification and kinetics of formation for cyanidin degradation products were obtained by high performance liquid chromatography system-mass spectrometry (HPLC-MS).

Original languageEnglish
Article number207
JournalFoods
Volume8
Issue number6
DOIs
StatePublished - Jun 2019

Keywords

  • Anthocyanins
  • Ascorbic acid
  • HPLC-MS
  • Kinetics
  • Shelf life
  • UV-Vis

All Science Journal Classification (ASJC) codes

  • Food Science
  • Microbiology
  • Health(social science)
  • Health Professions (miscellaneous)
  • Plant Science

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