Synthesis of Composition Tunable and Highly Luminescent Cesium Lead Halide Nanowires through Anion-Exchange Reactions

Dandan Zhang; Yiming Yang; Yehonadav Bekenstein; Yi Yu; Natalie A. Gibson; Andrew B. Wong; Samuel W. Eaton; Nikolay Kornienko; Qiao Kong; Minliang Lai; A. Paul Alivisatos; Stephen R. Leone; Peidong Yang

doi:10.1021/jacs.6b03134

Synthesis of Composition Tunable and Highly Luminescent Cesium Lead Halide Nanowires through Anion-Exchange Reactions

Dandan Zhang, Yiming Yang, Yehonadav Bekenstein, Yi Yu, Natalie A. Gibson, Andrew B. Wong, Samuel W. Eaton, Nikolay Kornienko, Qiao Kong, Minliang Lai, A. Paul Alivisatos, Stephen R. Leone, Peidong Yang

Research output: Contribution to journal › Article › peer-review

Abstract

Here, we demonstrate the successful synthesis of brightly emitting colloidal cesium lead halide (CsPbX₃, X = Cl, Br, I) nanowires (NWs) with uniform diameters and tunable compositions. By using highly monodisperse CsPbBr₃ NWs as templates, the NW composition can be independently controlled through anion-exchange reactions. CsPbX₃ alloy NWs with a wide range of alloy compositions can be achieved with well-preserved morphology and crystal structure. The NWs are highly luminescent with photoluminescence quantum yields (PLQY) ranging from 20% to 80%. The bright photoluminescence can be tuned over nearly the entire visible spectrum. The high PLQYs together with charge transport measurements exemplify the efficient alloying of the anionic sublattice in a one-dimensional CsPbX₃ system. The wires increased functionality in the form of fast photoresponse rates and the low defect density suggest CsPbX₃ NWs as prospective materials for optoelectronic applications.

Original language	English
Pages (from-to)	7236-7239
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	138
Issue number	23
DOIs	https://doi.org/10.1021/jacs.6b03134
State	Published - 15 Jun 2016
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/jacs.6b03134

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Zhang, D., Yang, Y., Bekenstein, Y., Yu, Y., Gibson, N. A., Wong, A. B., Eaton, S. W., Kornienko, N., Kong, Q., Lai, M., Alivisatos, A. P., Leone, S. R., & Yang, P. (2016). Synthesis of Composition Tunable and Highly Luminescent Cesium Lead Halide Nanowires through Anion-Exchange Reactions. Journal of the American Chemical Society, 138(23), 7236-7239. https://doi.org/10.1021/jacs.6b03134

@article{3712a50196a045a9a3f662bd1e8f9c85,

title = "Synthesis of Composition Tunable and Highly Luminescent Cesium Lead Halide Nanowires through Anion-Exchange Reactions",

abstract = "Here, we demonstrate the successful synthesis of brightly emitting colloidal cesium lead halide (CsPbX3, X = Cl, Br, I) nanowires (NWs) with uniform diameters and tunable compositions. By using highly monodisperse CsPbBr3 NWs as templates, the NW composition can be independently controlled through anion-exchange reactions. CsPbX3 alloy NWs with a wide range of alloy compositions can be achieved with well-preserved morphology and crystal structure. The NWs are highly luminescent with photoluminescence quantum yields (PLQY) ranging from 20\% to 80\%. The bright photoluminescence can be tuned over nearly the entire visible spectrum. The high PLQYs together with charge transport measurements exemplify the efficient alloying of the anionic sublattice in a one-dimensional CsPbX3 system. The wires increased functionality in the form of fast photoresponse rates and the low defect density suggest CsPbX3 NWs as prospective materials for optoelectronic applications.",

author = "Dandan Zhang and Yiming Yang and Yehonadav Bekenstein and Yi Yu and Gibson, \{Natalie A.\} and Wong, \{Andrew B.\} and Eaton, \{Samuel W.\} and Nikolay Kornienko and Qiao Kong and Minliang Lai and Alivisatos, \{A. Paul\} and Leone, \{Stephen R.\} and Peidong Yang",

note = "Publisher Copyright: {\textcopyright} 2016 American Chemical Society.",

year = "2016",

month = jun,

day = "15",

doi = "10.1021/jacs.6b03134",

language = "الإنجليزيّة",

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pages = "7236--7239",

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issn = "0002-7863",

publisher = "American Chemical Society",

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Zhang, D, Yang, Y, Bekenstein, Y, Yu, Y, Gibson, NA, Wong, AB, Eaton, SW, Kornienko, N, Kong, Q, Lai, M, Alivisatos, AP, Leone, SR & Yang, P 2016, 'Synthesis of Composition Tunable and Highly Luminescent Cesium Lead Halide Nanowires through Anion-Exchange Reactions', Journal of the American Chemical Society, vol. 138, no. 23, pp. 7236-7239. https://doi.org/10.1021/jacs.6b03134

TY - JOUR

T1 - Synthesis of Composition Tunable and Highly Luminescent Cesium Lead Halide Nanowires through Anion-Exchange Reactions

AU - Zhang, Dandan

AU - Yang, Yiming

AU - Bekenstein, Yehonadav

AU - Yu, Yi

AU - Gibson, Natalie A.

AU - Wong, Andrew B.

AU - Eaton, Samuel W.

AU - Kornienko, Nikolay

AU - Kong, Qiao

AU - Lai, Minliang

AU - Alivisatos, A. Paul

AU - Leone, Stephen R.

AU - Yang, Peidong

PY - 2016/6/15

Y1 - 2016/6/15

N2 - Here, we demonstrate the successful synthesis of brightly emitting colloidal cesium lead halide (CsPbX3, X = Cl, Br, I) nanowires (NWs) with uniform diameters and tunable compositions. By using highly monodisperse CsPbBr3 NWs as templates, the NW composition can be independently controlled through anion-exchange reactions. CsPbX3 alloy NWs with a wide range of alloy compositions can be achieved with well-preserved morphology and crystal structure. The NWs are highly luminescent with photoluminescence quantum yields (PLQY) ranging from 20% to 80%. The bright photoluminescence can be tuned over nearly the entire visible spectrum. The high PLQYs together with charge transport measurements exemplify the efficient alloying of the anionic sublattice in a one-dimensional CsPbX3 system. The wires increased functionality in the form of fast photoresponse rates and the low defect density suggest CsPbX3 NWs as prospective materials for optoelectronic applications.

AB - Here, we demonstrate the successful synthesis of brightly emitting colloidal cesium lead halide (CsPbX3, X = Cl, Br, I) nanowires (NWs) with uniform diameters and tunable compositions. By using highly monodisperse CsPbBr3 NWs as templates, the NW composition can be independently controlled through anion-exchange reactions. CsPbX3 alloy NWs with a wide range of alloy compositions can be achieved with well-preserved morphology and crystal structure. The NWs are highly luminescent with photoluminescence quantum yields (PLQY) ranging from 20% to 80%. The bright photoluminescence can be tuned over nearly the entire visible spectrum. The high PLQYs together with charge transport measurements exemplify the efficient alloying of the anionic sublattice in a one-dimensional CsPbX3 system. The wires increased functionality in the form of fast photoresponse rates and the low defect density suggest CsPbX3 NWs as prospective materials for optoelectronic applications.

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U2 - 10.1021/jacs.6b03134

DO - 10.1021/jacs.6b03134

M3 - مقالة

SN - 0002-7863

VL - 138

SP - 7236

EP - 7239

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 23

ER -

Synthesis of Composition Tunable and Highly Luminescent Cesium Lead Halide Nanowires through Anion-Exchange Reactions

Abstract

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