Abstract
A stable lithium stannenolate 7 was synthesized and isolated by the reaction of acylstannane 6 with LDA ortBu2MeSiLi in THF. 7 was characterized by X-ray crystallography and by NMR and UV-Vis spectroscopy. Spectroscopic and structural features, in combination with DFT quantum-mechanical calculations, indicate that 7 is best described as an acyl-substituted stannyl anion, adopting the stannenolate keto tautomeric structure.
Original language | English |
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Pages (from-to) | 13651-13655 |
Number of pages | 5 |
Journal | Dalton Transactions |
Volume | 50 |
Issue number | 39 |
DOIs | |
State | Published - 21 Oct 2021 |
All Science Journal Classification (ASJC) codes
- Inorganic Chemistry