Synthesis, isolation and characterization of a stable lithium stannenolate. A keto or an enol tautomer?

Roman Bashkurov, Natalia Fridman, Dmitry Bravo-Zhivotovskii, Yitzhak Apeloig

Research output: Contribution to journalArticlepeer-review

Abstract

A stable lithium stannenolate 7 was synthesized and isolated by the reaction of acylstannane 6 with LDA ortBu2MeSiLi in THF. 7 was characterized by X-ray crystallography and by NMR and UV-Vis spectroscopy. Spectroscopic and structural features, in combination with DFT quantum-mechanical calculations, indicate that 7 is best described as an acyl-substituted stannyl anion, adopting the stannenolate keto tautomeric structure.

Original languageEnglish
Pages (from-to)13651-13655
Number of pages5
JournalDalton Transactions
Volume50
Issue number39
DOIs
StatePublished - 21 Oct 2021

All Science Journal Classification (ASJC) codes

  • Inorganic Chemistry

Fingerprint

Dive into the research topics of 'Synthesis, isolation and characterization of a stable lithium stannenolate. A keto or an enol tautomer?'. Together they form a unique fingerprint.

Cite this