Synthesis and crystal structure of triphenyltin and lead complexes with organic peroxides

Alexander G. Medvedev; Mikhail Yu Sharipov; Dmitry A. Grishanov; Artur V. Eshtukov; Andrei V. Churakov; Ivan A. Buldashov; Pavel A. Egorov; Ovadia Lev; Petr V. Prikhodchenko

doi:10.1016/j.mencom.2022.01.018

Synthesis and crystal structure of triphenyltin and lead complexes with organic peroxides

Alexander G. Medvedev, Mikhail Yu Sharipov, Dmitry A. Grishanov, Artur V. Eshtukov, Andrei V. Churakov, Ivan A. Buldashov, Pavel A. Egorov, Ovadia Lev, Petr V. Prikhodchenko

Institute of Chemistry

The Hebrew University of Jerusalem

Research output: Contribution to journal › Article › peer-review

Abstract

Crystalline triphenyltin cumyl and tert-butyl peroxides (Ph₃SnOOCMe₂Ph and Ph₃SnOOBu^t, respectively) and triphenyllead cumyl peroxide (Ph₃PbOOCMe₂Ph) were synthesized and characterized by single crystal and powder X-ray diffraction, NMR, FTIR and Raman spectroscopies, TG and DSC analysis. The formation of triphenyltin tert-butyl peroxide in benzene in the presence of a base was proved by ¹¹⁹Sn, ¹³C and ¹H NMR spectroscopy. To the best of our knowledge, the obtained complexes are the first structurally characterized coordination compounds of tin and lead with organic peroxides.

Original language	English
Pages (from-to)	57-59
Number of pages	3
Journal	Mendeleev Communications
Volume	32
Issue number	1
DOIs	https://doi.org/10.1016/j.mencom.2022.01.018
State	Published - 1 Jan 2022

Keywords

Coordination peroxo compounds
Hydrogen peroxide
Lead
Organic hydroperoxides
Peroxo complexes
Tin

All Science Journal Classification (ASJC) codes

General Chemistry

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10.1016/j.mencom.2022.01.018

Cite this

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title = "Synthesis and crystal structure of triphenyltin and lead complexes with organic peroxides",

abstract = "Crystalline triphenyltin cumyl and tert-butyl peroxides (Ph3SnOOCMe2Ph and Ph3SnOOBut, respectively) and triphenyllead cumyl peroxide (Ph3PbOOCMe2Ph) were synthesized and characterized by single crystal and powder X-ray diffraction, NMR, FTIR and Raman spectroscopies, TG and DSC analysis. The formation of triphenyltin tert-butyl peroxide in benzene in the presence of a base was proved by 119Sn, 13C and 1H NMR spectroscopy. To the best of our knowledge, the obtained complexes are the first structurally characterized coordination compounds of tin and lead with organic peroxides.",

keywords = "Coordination peroxo compounds, Hydrogen peroxide, Lead, Organic hydroperoxides, Peroxo complexes, Tin",

author = "Medvedev, {Alexander G.} and Sharipov, {Mikhail Yu} and Grishanov, {Dmitry A.} and Eshtukov, {Artur V.} and Churakov, {Andrei V.} and Buldashov, {Ivan A.} and Egorov, {Pavel A.} and Ovadia Lev and Prikhodchenko, {Petr V.}",

note = "Publisher Copyright: {\textcopyright} 2022",

year = "2022",

month = jan,

day = "1",

doi = "10.1016/j.mencom.2022.01.018",

language = "الإنجليزيّة",

volume = "32",

pages = "57--59",

journal = "Mendeleev Communications",

issn = "0959-9436",

publisher = "Elsevier B.V.",

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TY - JOUR

T1 - Synthesis and crystal structure of triphenyltin and lead complexes with organic peroxides

AU - Medvedev, Alexander G.

AU - Sharipov, Mikhail Yu

AU - Grishanov, Dmitry A.

AU - Eshtukov, Artur V.

AU - Churakov, Andrei V.

AU - Buldashov, Ivan A.

AU - Egorov, Pavel A.

AU - Lev, Ovadia

AU - Prikhodchenko, Petr V.

PY - 2022/1/1

Y1 - 2022/1/1

N2 - Crystalline triphenyltin cumyl and tert-butyl peroxides (Ph3SnOOCMe2Ph and Ph3SnOOBut, respectively) and triphenyllead cumyl peroxide (Ph3PbOOCMe2Ph) were synthesized and characterized by single crystal and powder X-ray diffraction, NMR, FTIR and Raman spectroscopies, TG and DSC analysis. The formation of triphenyltin tert-butyl peroxide in benzene in the presence of a base was proved by 119Sn, 13C and 1H NMR spectroscopy. To the best of our knowledge, the obtained complexes are the first structurally characterized coordination compounds of tin and lead with organic peroxides.

AB - Crystalline triphenyltin cumyl and tert-butyl peroxides (Ph3SnOOCMe2Ph and Ph3SnOOBut, respectively) and triphenyllead cumyl peroxide (Ph3PbOOCMe2Ph) were synthesized and characterized by single crystal and powder X-ray diffraction, NMR, FTIR and Raman spectroscopies, TG and DSC analysis. The formation of triphenyltin tert-butyl peroxide in benzene in the presence of a base was proved by 119Sn, 13C and 1H NMR spectroscopy. To the best of our knowledge, the obtained complexes are the first structurally characterized coordination compounds of tin and lead with organic peroxides.

KW - Coordination peroxo compounds

KW - Hydrogen peroxide

KW - Lead

KW - Organic hydroperoxides

KW - Peroxo complexes

KW - Tin

UR - http://www.scopus.com/inward/record.url?scp=85125596563&partnerID=8YFLogxK

U2 - 10.1016/j.mencom.2022.01.018

DO - 10.1016/j.mencom.2022.01.018

M3 - مقالة

SN - 0959-9436

VL - 32

SP - 57

EP - 59

JO - Mendeleev Communications

JF - Mendeleev Communications

IS - 1

ER -

Synthesis and crystal structure of triphenyltin and lead complexes with organic peroxides

Abstract

Keywords

All Science Journal Classification (ASJC) codes

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