Synthese enantiomerenangereicherter, vicinaler tertiärer und quartärer Kohlenstoff-Stereozentren innerhalb einer acyclischen Kette

David Pierrot; Ilan Marek

doi:10.1002/ANGE.201903188

Synthese enantiomerenangereicherter, vicinaler tertiärer und quartärer Kohlenstoff-Stereozentren innerhalb einer acyclischen Kette

Translated title of the contribution: Synthesis of Enantioenriched Vicinal Tertiary and Quaternary Carbon Stereogenic Centers within an Acyclic Chain

David Pierrot, Ilan Marek

Chemistry

Technion - Israel Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

Overcoming the inherent difficulty to prepare quaternary carbon stereogenic centers, the diastereo- and enantioselective preparation of acyclic carbon backbones possessing vicinal quaternary and tertiary stereogenic centers (i.e. in a 1,2-relationship) causes distorted geometries and represents a very acute problem in organic synthesis. Several approaches are discussed in this minireview underlining the challenges illustrated by the rather limited number of approaches available to practitioners.

Translated title of the contribution	Synthesis of Enantioenriched Vicinal Tertiary and Quaternary Carbon Stereogenic Centers within an Acyclic Chain
Original language	German
Pages (from-to)	36-49
Number of pages	14
Journal	Advanced Materials
Volume	132
Issue number	1
DOIs	https://doi.org/10.1002/ANGE.201903188
State	Published - 2020

All Science Journal Classification (ASJC) codes

Mechanics of Materials
Mechanical Engineering
General Materials Science

Access to Document

10.1002/ANGE.201903188

Cite this

@article{9f87dbe9b7ad43c89ba75da68e5001fa,

title = "Synthese enantiomerenangereicherter, vicinaler terti{\"a}rer und quart{\"a}rer Kohlenstoff-Stereozentren innerhalb einer acyclischen Kette",

abstract = "Overcoming the inherent difficulty to prepare quaternary carbon stereogenic centers, the diastereo- and enantioselective preparation of acyclic carbon backbones possessing vicinal quaternary and tertiary stereogenic centers (i.e. in a 1,2-relationship) causes distorted geometries and represents a very acute problem in organic synthesis. Several approaches are discussed in this minireview underlining the challenges illustrated by the rather limited number of approaches available to practitioners.",

author = "David Pierrot and Ilan Marek",

note = "Publisher Copyright: {\textcopyright} 2020 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim.",

year = "2020",

doi = "10.1002/ANGE.201903188",

language = "ألمانيّة",

volume = "132",

pages = "36--49",

journal = "Advanced Materials",

issn = "0935-9648",

publisher = "Wiley-Blackwell",

number = "1",

}

TY - JOUR

T1 - Synthese enantiomerenangereicherter, vicinaler tertiärer und quartärer Kohlenstoff-Stereozentren innerhalb einer acyclischen Kette

AU - Pierrot, David

AU - Marek, Ilan

PY - 2020

Y1 - 2020

N2 - Overcoming the inherent difficulty to prepare quaternary carbon stereogenic centers, the diastereo- and enantioselective preparation of acyclic carbon backbones possessing vicinal quaternary and tertiary stereogenic centers (i.e. in a 1,2-relationship) causes distorted geometries and represents a very acute problem in organic synthesis. Several approaches are discussed in this minireview underlining the challenges illustrated by the rather limited number of approaches available to practitioners.

AB - Overcoming the inherent difficulty to prepare quaternary carbon stereogenic centers, the diastereo- and enantioselective preparation of acyclic carbon backbones possessing vicinal quaternary and tertiary stereogenic centers (i.e. in a 1,2-relationship) causes distorted geometries and represents a very acute problem in organic synthesis. Several approaches are discussed in this minireview underlining the challenges illustrated by the rather limited number of approaches available to practitioners.

UR - http://www.scopus.com/inward/record.url?scp=85070099357&partnerID=8YFLogxK

U2 - 10.1002/ANGE.201903188

DO - 10.1002/ANGE.201903188

M3 - مقالة

SN - 0935-9648

VL - 132

SP - 36

EP - 49

JO - Advanced Materials

JF - Advanced Materials

IS - 1

ER -

Synthese enantiomerenangereicherter, vicinaler tertiärer und quartärer Kohlenstoff-Stereozentren innerhalb einer acyclischen Kette

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this