syn-(Me,Me)Bimane as a Structural Building Block in Metal Coordination Architectures

Yael Diskin-Posner; Sara Amer; Ankana Roy; Partha Jyoti Das; Flavio Grynszpan; Michael Montag

doi:10.1021/acs.cgd.9b00089

syn-(Me,Me)Bimane as a Structural Building Block in Metal Coordination Architectures

Yael Diskin-Posner, Sara Amer, Ankana Roy, Partha Jyoti Das, Flavio Grynszpan, Michael Montag

Weizmann Institute of Science, Ariel University

Research output: Contribution to journal › Article › peer-review

Abstract

Li(I) and Na(I) complexes of the fluorescent dye syn-(Me,Me)bimane were isolated and crystallographically characterized, revealing the bimane as a principal component in diverse coordination topologies, including discrete and polymeric structures. The bimane exhibits multiple functions in these frameworks, acting as a variable-denticity O-donor ligand, pi-stacking unit, and hydrogen bond acceptor. These features highlight a new role for syn-bimanes, not as fluorophores, but as versatile building blocks in metal coordination architectures.

Original language	English
Pages (from-to)	4358-4368
Number of pages	11
Journal	Crystal Growth and Design
Volume	19
Issue number	8
Early online date	25 Jun 2019
DOIs	https://doi.org/10.1021/acs.cgd.9b00089
State	Published - 7 Aug 2019

All Science Journal Classification (ASJC) codes

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1021/acs.cgd.9b00089

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title = "syn-(Me,Me)Bimane as a Structural Building Block in Metal Coordination Architectures",

abstract = "Li(I) and Na(I) complexes of the fluorescent dye syn-(Me,Me)bimane were isolated and crystallographically characterized, revealing the bimane as a principal component in diverse coordination topologies, including discrete and polymeric structures. The bimane exhibits multiple functions in these frameworks, acting as a variable-denticity O-donor ligand, pi-stacking unit, and hydrogen bond acceptor. These features highlight a new role for syn-bimanes, not as fluorophores, but as versatile building blocks in metal coordination architectures.",

author = "Yael Diskin-Posner and Sara Amer and Ankana Roy and Das, \{Partha Jyoti\} and Flavio Grynszpan and Michael Montag",

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doi = "10.1021/acs.cgd.9b00089",

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AU - Diskin-Posner, Yael

AU - Amer, Sara

AU - Roy, Ankana

AU - Das, Partha Jyoti

AU - Grynszpan, Flavio

AU - Montag, Michael

PY - 2019/8/7

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N2 - Li(I) and Na(I) complexes of the fluorescent dye syn-(Me,Me)bimane were isolated and crystallographically characterized, revealing the bimane as a principal component in diverse coordination topologies, including discrete and polymeric structures. The bimane exhibits multiple functions in these frameworks, acting as a variable-denticity O-donor ligand, pi-stacking unit, and hydrogen bond acceptor. These features highlight a new role for syn-bimanes, not as fluorophores, but as versatile building blocks in metal coordination architectures.

AB - Li(I) and Na(I) complexes of the fluorescent dye syn-(Me,Me)bimane were isolated and crystallographically characterized, revealing the bimane as a principal component in diverse coordination topologies, including discrete and polymeric structures. The bimane exhibits multiple functions in these frameworks, acting as a variable-denticity O-donor ligand, pi-stacking unit, and hydrogen bond acceptor. These features highlight a new role for syn-bimanes, not as fluorophores, but as versatile building blocks in metal coordination architectures.

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U2 - 10.1021/acs.cgd.9b00089

DO - 10.1021/acs.cgd.9b00089

M3 - مقالة

SN - 1528-7483

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SP - 4358

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JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 8

ER -

syn-(Me,Me)Bimane as a Structural Building Block in Metal Coordination Architectures

Abstract

All Science Journal Classification (ASJC) codes

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