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Strongly Coupled Quantum Heat Machines

Research output: Contribution to journalArticlepeer-review

Abstract

Energy conversion of heat into work at the quantum level is modeled by quantum heat machines (QHMs) generally assumed to operate at weak coupling to the baths. This supposition is grounded in the separability principle between systems and allows the derivation of the evolution equation. In the weak coupling regime, the machine's output is limited by the coupling strength, restricting their application. Seeking to overcome this limitation, we analyze QHMs in the virtually unexplored strong coupling regime here, where separability, as well as other standard thermodynamic assumptions, may no longer hold. We show that strongly coupled QHMs may be as efficient as their weakly coupled counterparts. In addition, we find a novel turnover behavior where their output saturates and disappears in the limit of ultrastrong coupling.

Original languageEnglish GB
Pages (from-to)3477-3482
Number of pages6
JournalJournal of Physical Chemistry Letters
Volume6
Issue number17
DOIs
StatePublished - 18 Aug 2015
Externally publishedYes

Keywords

  • Energy conversion
  • Open quantum systems
  • Polaron transformation
  • Quantum heat machines
  • Strong coupling

ASJC Scopus subject areas

  • General Materials Science
  • Physical and Theoretical Chemistry

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