Stoichiometric metal-free reduction of CO in syn-gas

Roman Dobrovetsky; Douglas W. Stephan

doi:10.1021/ja401492s

Stoichiometric metal-free reduction of CO in syn-gas

Research output: Contribution to journal › Article › peer-review

Abstract

Reaction of a 2:1 mixture of B(C₆F₅)₃ and tBu₃P with syn-gas results in the stoichiometric reduction of CO to give a formyl derivative which reacts further via an epoxy-borate intermediate to capture CO, affording a heterocylic alkoxyborate. Heating the reaction prompts reaction with H₂ to give a borane-oxy-borate derivative, the product of C-O bond cleavage.

Original language	English
Pages (from-to)	4974-4977
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	135
Issue number	13
DOIs	https://doi.org/10.1021/ja401492s
State	Published - 3 Apr 2013
Externally published	Yes

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja401492s

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title = "Stoichiometric metal-free reduction of CO in syn-gas",

abstract = "Reaction of a 2:1 mixture of B(C6F5)3 and tBu3P with syn-gas results in the stoichiometric reduction of CO to give a formyl derivative which reacts further via an epoxy-borate intermediate to capture CO, affording a heterocylic alkoxyborate. Heating the reaction prompts reaction with H2 to give a borane-oxy-borate derivative, the product of C-O bond cleavage.",

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doi = "10.1021/ja401492s",

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AB - Reaction of a 2:1 mixture of B(C6F5)3 and tBu3P with syn-gas results in the stoichiometric reduction of CO to give a formyl derivative which reacts further via an epoxy-borate intermediate to capture CO, affording a heterocylic alkoxyborate. Heating the reaction prompts reaction with H2 to give a borane-oxy-borate derivative, the product of C-O bond cleavage.

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Stoichiometric metal-free reduction of CO in syn-gas

Abstract

All Science Journal Classification (ASJC) codes

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