Spin-dependent Enantioselective Electropolymerization

Francesco Tassinari; Dana Amsallem; Brian P. Bloom; Yiyang Lu; Anjan Bedi; David H. Waldeck; Ori Gidron; Ron Naaman

doi:10.1021/acs.jpcc.0c06238

Spin-dependent Enantioselective Electropolymerization

Francesco Tassinari, Dana Amsallem, Brian P. Bloom, Yiyang Lu, Anjan Bedi, David H. Waldeck, Ori Gidron, Ron Naaman

Weizmann Institute of Science, The Hebrew University of Jerusalem

Research output: Contribution to journal › Article › peer-review

Abstract

The electro-oxidative polymerization mechanism of an enantiopure chiral EDOT monomer, performed using spin polarized currents, is shown to depend on the electron spin orientation. The spin-polarized current is shown to influence the initial nucleation rate of the polymerization reaction. This observation is rationalized in the framework of the Chiral Induced Spin Selectivity effect.

Original language	English
Pages (from-to)	20974-20980
Number of pages	7
Journal	Journal of Physical chemistry c
Volume	124
Issue number	38
Early online date	31 Aug 2020
DOIs	https://doi.org/10.1021/acs.jpcc.0c06238
State	Published - 24 Sep 2020

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
General Energy
Physical and Theoretical Chemistry
Surfaces, Coatings and Films

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10.1021/acs.jpcc.0c06238License: CC BY

Cite this

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title = "Spin-dependent Enantioselective Electropolymerization",

abstract = "The electro-oxidative polymerization mechanism of an enantiopure chiral EDOT monomer, performed using spin polarized currents, is shown to depend on the electron spin orientation. The spin-polarized current is shown to influence the initial nucleation rate of the polymerization reaction. This observation is rationalized in the framework of the Chiral Induced Spin Selectivity effect.",

author = "Francesco Tassinari and Dana Amsallem and Bloom, \{Brian P.\} and Yiyang Lu and Anjan Bedi and Waldeck, \{David H.\} and Ori Gidron and Ron Naaman",

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doi = "10.1021/acs.jpcc.0c06238",

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AU - Tassinari, Francesco

AU - Amsallem, Dana

AU - Bloom, Brian P.

AU - Lu, Yiyang

AU - Bedi, Anjan

AU - Waldeck, David H.

AU - Gidron, Ori

AU - Naaman, Ron

PY - 2020/9/24

Y1 - 2020/9/24

N2 - The electro-oxidative polymerization mechanism of an enantiopure chiral EDOT monomer, performed using spin polarized currents, is shown to depend on the electron spin orientation. The spin-polarized current is shown to influence the initial nucleation rate of the polymerization reaction. This observation is rationalized in the framework of the Chiral Induced Spin Selectivity effect.

AB - The electro-oxidative polymerization mechanism of an enantiopure chiral EDOT monomer, performed using spin polarized currents, is shown to depend on the electron spin orientation. The spin-polarized current is shown to influence the initial nucleation rate of the polymerization reaction. This observation is rationalized in the framework of the Chiral Induced Spin Selectivity effect.

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U2 - 10.1021/acs.jpcc.0c06238

DO - 10.1021/acs.jpcc.0c06238

M3 - مقالة

SN - 1932-7447

VL - 124

SP - 20974

EP - 20980

JO - Journal of Physical chemistry c

JF - Journal of Physical chemistry c

IS - 38

ER -

Spin-dependent Enantioselective Electropolymerization

Abstract

All Science Journal Classification (ASJC) codes

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