Salt-controlled selectivity in "on water" and "in Water" passerini-type multicomponent reactions

Tal Sela; Arkadi Vigalok

doi:https://doi.org/10.1002/adsc.201200448

Salt-controlled selectivity in "on water" and "in Water" passerini-type multicomponent reactions

Tal Sela, Arkadi Vigalok

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

Abstract

We have demonstrated that simple sodium salts can completely reverse the product ratios of the Passerini reaction in aqueous media. Furthermore, the use of the "salting-in" salt and a small excess of the nucleophile gives significantly higher yields than the use of the saturated solution of the nucleophile alone.

Original language	English
Pages (from-to)	2407-2411
Number of pages	5
Journal	Advanced Synthesis and Catalysis
Volume	354
Issue number	13
DOIs	https://doi.org/10.1002/adsc.201200448
State	Published - 17 Sep 2012

Keywords

Hofmeister series
Passerini reaction
in water
on water
salt effect

All Science Journal Classification (ASJC) codes

Catalysis
Organic Chemistry

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https://doi.org/10.1002/adsc.201200448

Cite this

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T1 - Salt-controlled selectivity in "on water" and "in Water" passerini-type multicomponent reactions

AU - Sela, Tal

AU - Vigalok, Arkadi

PY - 2012/9/17

Y1 - 2012/9/17

N2 - We have demonstrated that simple sodium salts can completely reverse the product ratios of the Passerini reaction in aqueous media. Furthermore, the use of the "salting-in" salt and a small excess of the nucleophile gives significantly higher yields than the use of the saturated solution of the nucleophile alone.

AB - We have demonstrated that simple sodium salts can completely reverse the product ratios of the Passerini reaction in aqueous media. Furthermore, the use of the "salting-in" salt and a small excess of the nucleophile gives significantly higher yields than the use of the saturated solution of the nucleophile alone.

KW - Hofmeister series

KW - Passerini reaction

KW - in water

KW - on water

KW - salt effect

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DO - https://doi.org/10.1002/adsc.201200448

M3 - مقالة

SN - 1615-4150

VL - 354

SP - 2407

EP - 2411

JO - Advanced Synthesis and Catalysis

JF - Advanced Synthesis and Catalysis

IS - 13

ER -

Salt-controlled selectivity in "on water" and "in Water" passerini-type multicomponent reactions

Abstract

Keywords

All Science Journal Classification (ASJC) codes

Access to Document

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