Ru-catalyzed isomerization of ω-alkenylboronates towards stereoselective synthesis of vinylboronates with subsequent: In situ functionalization

Guo-Ming Ho; Lucas Segura; Ilan Marek

doi:10.1039/d0sc02542a

Ru-catalyzed isomerization of ω-alkenylboronates towards stereoselective synthesis of vinylboronates with subsequent: In situ functionalization

Guo-Ming Ho, Lucas Segura, Ilan Marek

Technion - Israel Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

The stereoselective preparation of synthetically versatile vinylboronates from ω-alkenylboronates is achieved through a ruthenium-catalyzed isomerization reaction. A variety of di- A nd trisubstituted vinylboronates were conveniently produced and could be used as a new starting point for subsequent in situ remote functionalization through either a sequential Ru/Pd or Ru/Cu double catalytic system.

Original language	English
Pages (from-to)	5944-5949
Number of pages	6
Journal	Chemical Science
Volume	11
Issue number	23
DOIs	https://doi.org/10.1039/d0sc02542a
State	Published - 21 Jun 2020

All Science Journal Classification (ASJC) codes

General Chemistry

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abstract = "The stereoselective preparation of synthetically versatile vinylboronates from ω-alkenylboronates is achieved through a ruthenium-catalyzed isomerization reaction. A variety of di- A nd trisubstituted vinylboronates were conveniently produced and could be used as a new starting point for subsequent in situ remote functionalization through either a sequential Ru/Pd or Ru/Cu double catalytic system. ",

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AU - Segura, Lucas

AU - Marek, Ilan

PY - 2020/6/21

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AB - The stereoselective preparation of synthetically versatile vinylboronates from ω-alkenylboronates is achieved through a ruthenium-catalyzed isomerization reaction. A variety of di- A nd trisubstituted vinylboronates were conveniently produced and could be used as a new starting point for subsequent in situ remote functionalization through either a sequential Ru/Pd or Ru/Cu double catalytic system.

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DO - 10.1039/d0sc02542a

M3 - مقالة

SN - 2041-6520

VL - 11

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JO - Chemical Science

JF - Chemical Science

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ER -

Ru-catalyzed isomerization of ω-alkenylboronates towards stereoselective synthesis of vinylboronates with subsequent: In situ functionalization

Abstract

All Science Journal Classification (ASJC) codes

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