Rhodium-Catalyzed Arylation of Cyclopropenes Based on Asymmetric Direct Functionalization of Three-Membered Carbocycles

Longyang Dian; Ilan Marek

doi:10.1002/anie.201713324

Rhodium-Catalyzed Arylation of Cyclopropenes Based on Asymmetric Direct Functionalization of Three-Membered Carbocycles

Longyang Dian, Ilan Marek

Technion - Israel Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

A variety of highly diastereo- and enantiomerically enriched arylcyclopropanes is obtained through the asymmetric rhodium-catalyzed arylation reaction of achiral nonfunctionalized cyclopropene derivatives with commercially available aryl boronic acids in the presence of (R,S)-Josiphos.

Original language	English
Pages (from-to)	3682-3686
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	57
Issue number	14
DOIs	https://doi.org/10.1002/anie.201713324
State	Published - 26 Mar 2018

Keywords

asymmetric catalysis
boronic acids
carbometalation
cyclopropanes
rhodium

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry

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10.1002/anie.201713324

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title = "Rhodium-Catalyzed Arylation of Cyclopropenes Based on Asymmetric Direct Functionalization of Three-Membered Carbocycles",

abstract = "A variety of highly diastereo- and enantiomerically enriched arylcyclopropanes is obtained through the asymmetric rhodium-catalyzed arylation reaction of achiral nonfunctionalized cyclopropene derivatives with commercially available aryl boronic acids in the presence of (R,S)-Josiphos.",

keywords = "asymmetric catalysis, boronic acids, carbometalation, cyclopropanes, rhodium",

author = "Longyang Dian and Ilan Marek",

note = "Publisher Copyright: {\textcopyright} 2018 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2018",

month = mar,

day = "26",

doi = "10.1002/anie.201713324",

language = "الإنجليزيّة",

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T1 - Rhodium-Catalyzed Arylation of Cyclopropenes Based on Asymmetric Direct Functionalization of Three-Membered Carbocycles

AU - Dian, Longyang

AU - Marek, Ilan

PY - 2018/3/26

Y1 - 2018/3/26

N2 - A variety of highly diastereo- and enantiomerically enriched arylcyclopropanes is obtained through the asymmetric rhodium-catalyzed arylation reaction of achiral nonfunctionalized cyclopropene derivatives with commercially available aryl boronic acids in the presence of (R,S)-Josiphos.

AB - A variety of highly diastereo- and enantiomerically enriched arylcyclopropanes is obtained through the asymmetric rhodium-catalyzed arylation reaction of achiral nonfunctionalized cyclopropene derivatives with commercially available aryl boronic acids in the presence of (R,S)-Josiphos.

KW - asymmetric catalysis

KW - boronic acids

KW - carbometalation

KW - cyclopropanes

KW - rhodium

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U2 - 10.1002/anie.201713324

DO - 10.1002/anie.201713324

M3 - مقالة

SN - 1433-7851

VL - 57

SP - 3682

EP - 3686

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 14

ER -

Rhodium-Catalyzed Arylation of Cyclopropenes Based on Asymmetric Direct Functionalization of Three-Membered Carbocycles

Abstract

Keywords

All Science Journal Classification (ASJC) codes

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