Revealing true coupling strengths in two-dimensional spectroscopy with sparsity-based signal recovery

Hadas Frostig; Tim Bayer; Yonina C. Eldar; Yaron Silberberg

doi:https://doi.org/10.1038/lsa.2017.115

Revealing true coupling strengths in two-dimensional spectroscopy with sparsity-based signal recovery

Hadas Frostig, Tim Bayer, Yonina C. Eldar, Yaron Silberberg

Weizmann Institute Of Science, Technion - Israel Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

Two-dimensional (2D) spectroscopy is used to study the interactions between energy levels in both the field of optics and nuclear magnetic resonance (NMR). Conventionally, the strength of interaction between two levels is inferred from the value of their common off-diagonal peak in the 2D spectrum, which is termed the cross peak. However, stronger diagonal peaks often have long tails that extend into the locations of the cross peaks and alter their values. Here, we introduce a method for retrieving the true interaction strengths by using sparse signal recovery techniques and apply our method in 2D Raman spectroscopy experiments.

Original language	English
Article number	17115
Number of pages	6
Journal	Light: Science and Applications
Volume	6
Issue number	12
Early online date	7 Aug 2017
DOIs	https://doi.org/10.1038/lsa.2017.115
State	Published - Dec 2017

Keywords

multidimensional spectroscopy
nonlinear optics
sparsity-based algorithms

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
Atomic and Molecular Physics, and Optics

Access to Document

https://doi.org/10.1038/lsa.2017.115License: CC BY-NC-ND

Cite this

@article{c90692d7187c4fdc95f66b25fb6a01ae,

title = "Revealing true coupling strengths in two-dimensional spectroscopy with sparsity-based signal recovery",

abstract = "Two-dimensional (2D) spectroscopy is used to study the interactions between energy levels in both the field of optics and nuclear magnetic resonance (NMR). Conventionally, the strength of interaction between two levels is inferred from the value of their common off-diagonal peak in the 2D spectrum, which is termed the cross peak. However, stronger diagonal peaks often have long tails that extend into the locations of the cross peaks and alter their values. Here, we introduce a method for retrieving the true interaction strengths by using sparse signal recovery techniques and apply our method in 2D Raman spectroscopy experiments.",

keywords = "multidimensional spectroscopy, nonlinear optics, sparsity-based algorithms",

author = "Hadas Frostig and Tim Bayer and Eldar, {Yonina C.} and Yaron Silberberg",

note = "We would like to thank JC Hoch, N Dudovich and L Chuntonov for helpful discussions. This work was supported by Icore (Israeli centres of research excellence of the ISF), and the Crown Photonics Center. HF, TB, YCE and YS conceived the idea, developed and performed BOMP analysis. HF and YS wrote the manuscript.",

year = "2017",

month = dec,

doi = "https://doi.org/10.1038/lsa.2017.115",

language = "الإنجليزيّة",

volume = "6",

journal = "Light: Science and Applications",

issn = "2047-7538",

publisher = "Nature Publishing Group",

number = "12",

}

TY - JOUR

T1 - Revealing true coupling strengths in two-dimensional spectroscopy with sparsity-based signal recovery

AU - Frostig, Hadas

AU - Bayer, Tim

AU - Eldar, Yonina C.

AU - Silberberg, Yaron

N1 - We would like to thank JC Hoch, N Dudovich and L Chuntonov for helpful discussions. This work was supported by Icore (Israeli centres of research excellence of the ISF), and the Crown Photonics Center. HF, TB, YCE and YS conceived the idea, developed and performed BOMP analysis. HF and YS wrote the manuscript.

PY - 2017/12

Y1 - 2017/12

N2 - Two-dimensional (2D) spectroscopy is used to study the interactions between energy levels in both the field of optics and nuclear magnetic resonance (NMR). Conventionally, the strength of interaction between two levels is inferred from the value of their common off-diagonal peak in the 2D spectrum, which is termed the cross peak. However, stronger diagonal peaks often have long tails that extend into the locations of the cross peaks and alter their values. Here, we introduce a method for retrieving the true interaction strengths by using sparse signal recovery techniques and apply our method in 2D Raman spectroscopy experiments.

AB - Two-dimensional (2D) spectroscopy is used to study the interactions between energy levels in both the field of optics and nuclear magnetic resonance (NMR). Conventionally, the strength of interaction between two levels is inferred from the value of their common off-diagonal peak in the 2D spectrum, which is termed the cross peak. However, stronger diagonal peaks often have long tails that extend into the locations of the cross peaks and alter their values. Here, we introduce a method for retrieving the true interaction strengths by using sparse signal recovery techniques and apply our method in 2D Raman spectroscopy experiments.

KW - multidimensional spectroscopy

KW - nonlinear optics

KW - sparsity-based algorithms

UR - http://www.scopus.com/inward/record.url?scp=85065786730&partnerID=8YFLogxK

U2 - https://doi.org/10.1038/lsa.2017.115

DO - https://doi.org/10.1038/lsa.2017.115

M3 - مقالة

C2 - 30167224

SN - 2047-7538

VL - 6

JO - Light: Science and Applications

JF - Light: Science and Applications

IS - 12

M1 - 17115

ER -

Revealing true coupling strengths in two-dimensional spectroscopy with sparsity-based signal recovery

Abstract

Keywords

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this