Abstract
Ion-exchange (IX) is common for separating NO3− from drinking water. From both cost and environmental perspectives, the IX regeneration brine must be recycled, via nitrate reduction to N2(g) . Nano zero-valent iron (nZVI) reduces nitrate efficiently to ammonia, under brine conditions. However, to be sustainable, the formed ammonia should be oxidized. Accordingly, a new process was developed, comprising IX separation, nZVI-based nitrate removal from the IX regeneration brine, followed by indirect ammonia electro-oxidation. The aim was to convert nitrate to N2(g) while allowing repeated usage of the NaCl brine for multiple IX cycles. All process steps were experimentally examined and shown to be feasible: nitrate was efficiently separated using IX, which was subsequently regenerated with the treated/recovered NaCl brine. The nitrate released to the brine reacted with nZVI, generating ammonia and Fe(II). Fresh nZVI particles were reproduced from the resulting brine, which contained Fe(II), Na+, Cl− and ammonia. The ammonia in the nZVI production procedure filtrate was indirectly electro-oxidized to N2(g) at the inherent high Cl− concentration, which prepared the brine for the next IX regeneration cycle. The dominant reaction between nZVI and NO3− was described best (Wilcoxon test) by 4Fe(s) + 10H+ + NO3− → 4Fe2+ + NH4+ + 3H2O, and proceeded at >5 mmol·L−1·min−1 at room temperature and 3 < pH < 5.
Original language | English |
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Article number | 2 |
Pages (from-to) | 1-19 |
Number of pages | 19 |
Journal | ChemEngineering |
Volume | 1 |
Issue number | 1 |
DOIs | |
State | Published - Sep 2017 |
Keywords
- Drinking water
- Electrooxidation
- Ion exchange
- NZVI
- Nitrate reduction
All Science Journal Classification (ASJC) codes
- General Engineering
- General Chemical Engineering
- General Energy