Relativistic calculations on the electric dipole transition probabilities of the RbAr exciplex

Alexander A. Medvedev; Andrey V. Stolyarov; Andréi Zaitsevskii; Ephraim Eliav

Relativistic calculations on the electric dipole transition probabilities of the RbAr exciplex

Alexander A. Medvedev, Andrey V. Stolyarov, Andréi Zaitsevskii, Ephraim Eliav

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

Abstract

Accurate evaluation of electric dipole (E1) transition probabilities in exciplexes formed by an alkali atom (M) and rare gas (Rg) atom(s) is essential for modelling optically pumped M–Rg laser media. We present a simple finite-difference scheme of ab initio calculations of E1 transition moments in the RbAr exciplex in the frames of relativistic Fock space coupled cluster approach.

Original language	English
Pages (from-to)	205-209
Number of pages	5
Journal	Nonlinear Phenomena in Complex Systems
Volume	20
Issue number	2
State	Published - 2017

Keywords

Electric dipole transition moments
Excited states
Multireference coupled cluster method
Relativistic electronic structure modeling
Spin-orbit interactions
Two-component pseudopotentials

All Science Journal Classification (ASJC) codes

Statistical and Nonlinear Physics
Mathematical Physics

Cite this

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title = "Relativistic calculations on the electric dipole transition probabilities of the RbAr exciplex",

abstract = "Accurate evaluation of electric dipole (E1) transition probabilities in exciplexes formed by an alkali atom (M) and rare gas (Rg) atom(s) is essential for modelling optically pumped M–Rg laser media. We present a simple finite-difference scheme of ab initio calculations of E1 transition moments in the RbAr exciplex in the frames of relativistic Fock space coupled cluster approach.",

keywords = "Electric dipole transition moments, Excited states, Multireference coupled cluster method, Relativistic electronic structure modeling, Spin-orbit interactions, Two-component pseudopotentials",

author = "Medvedev, {Alexander A.} and Stolyarov, {Andrey V.} and Andr{\'e}i Zaitsevskii and Ephraim Eliav",

year = "2017",

language = "الإنجليزيّة",

volume = "20",

pages = "205--209",

journal = "Nonlinear Phenomena in Complex Systems",

issn = "1561-4085",

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number = "2",

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TY - JOUR

T1 - Relativistic calculations on the electric dipole transition probabilities of the RbAr exciplex

AU - Medvedev, Alexander A.

AU - Stolyarov, Andrey V.

AU - Zaitsevskii, Andréi

AU - Eliav, Ephraim

PY - 2017

Y1 - 2017

N2 - Accurate evaluation of electric dipole (E1) transition probabilities in exciplexes formed by an alkali atom (M) and rare gas (Rg) atom(s) is essential for modelling optically pumped M–Rg laser media. We present a simple finite-difference scheme of ab initio calculations of E1 transition moments in the RbAr exciplex in the frames of relativistic Fock space coupled cluster approach.

AB - Accurate evaluation of electric dipole (E1) transition probabilities in exciplexes formed by an alkali atom (M) and rare gas (Rg) atom(s) is essential for modelling optically pumped M–Rg laser media. We present a simple finite-difference scheme of ab initio calculations of E1 transition moments in the RbAr exciplex in the frames of relativistic Fock space coupled cluster approach.

KW - Electric dipole transition moments

KW - Excited states

KW - Multireference coupled cluster method

KW - Relativistic electronic structure modeling

KW - Spin-orbit interactions

KW - Two-component pseudopotentials

UR - http://www.scopus.com/inward/record.url?scp=85021902962&partnerID=8YFLogxK

M3 - مقالة

SN - 1561-4085

VL - 20

SP - 205

EP - 209

JO - Nonlinear Phenomena in Complex Systems

JF - Nonlinear Phenomena in Complex Systems

IS - 2

ER -

Relativistic calculations on the electric dipole transition probabilities of the RbAr exciplex

Abstract

Keywords

All Science Journal Classification (ASJC) codes

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