Abstract
The regio- and stereoselective preparation of fully substituted and stereodefined silyl enol ethers of ketones and aldehydes through an allyl-Brook rearrangement is reported. This fast and efficient method proceeds from a mixture of E and Z isomers of easily accessible starting materials.
| Original language | English |
|---|---|
| Pages (from-to) | 14995-14999 |
| Number of pages | 5 |
| Journal | Angewandte Chemie - International Edition |
| Volume | 58 |
| Issue number | 42 |
| DOIs | |
| State | Published - 14 Oct 2019 |
Keywords
- Brook rearrangement
- carbonyl compounds
- hydroxy silanes
- silyl enol ethers
- stereochemistry
ASJC Scopus subject areas
- Catalysis
- General Chemistry
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