Regio- and Diastereoselective Copper-Catalyzed Carbometalation of Cyclopropenylsilanes

Yair Cohen; Ilan Marek

doi:10.1021/acs.orglett.9b03531

Regio- and Diastereoselective Copper-Catalyzed Carbometalation of Cyclopropenylsilanes

Yair Cohen
, Ilan Marek

Technion - Israel Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

We therein report a regio- and diastereoselective copper-catalyzed carbometalation of enantioenriched readily available cyclopropenylsilanes as a synthetic tool to access a large family of stereodefined fully-(hexa)-substituted cyclopropanes.

Original language	English GB
Pages (from-to)	9162-9165
Number of pages	4
Journal	Organic Letters
Volume	21
Issue number	22
DOIs	https://doi.org/10.1021/acs.orglett.9b03531
State	Published - 15 Nov 2019

ASJC Scopus subject areas

Biochemistry
Physical and Theoretical Chemistry
Organic Chemistry

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10.1021/acs.orglett.9b03531

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title = "Regio- and Diastereoselective Copper-Catalyzed Carbometalation of Cyclopropenylsilanes",

abstract = "We therein report a regio- and diastereoselective copper-catalyzed carbometalation of enantioenriched readily available cyclopropenylsilanes as a synthetic tool to access a large family of stereodefined fully-(hexa)-substituted cyclopropanes.",

author = "Yair Cohen and Ilan Marek",

note = "Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

year = "2019",

month = nov,

day = "15",

doi = "10.1021/acs.orglett.9b03531",

language = "الإنجليزيّة",

volume = "21",

pages = "9162--9165",

journal = "Organic Letters",

issn = "1523-7060",

publisher = "American Chemical Society",

number = "22",

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T1 - Regio- and Diastereoselective Copper-Catalyzed Carbometalation of Cyclopropenylsilanes

AU - Cohen, Yair

AU - Marek, Ilan

PY - 2019/11/15

Y1 - 2019/11/15

N2 - We therein report a regio- and diastereoselective copper-catalyzed carbometalation of enantioenriched readily available cyclopropenylsilanes as a synthetic tool to access a large family of stereodefined fully-(hexa)-substituted cyclopropanes.

AB - We therein report a regio- and diastereoselective copper-catalyzed carbometalation of enantioenriched readily available cyclopropenylsilanes as a synthetic tool to access a large family of stereodefined fully-(hexa)-substituted cyclopropanes.

UR - https://www.scopus.com/pages/publications/85074720144

U2 - 10.1021/acs.orglett.9b03531

DO - 10.1021/acs.orglett.9b03531

M3 - مقالة

SN - 1523-7060

VL - 21

SP - 9162

EP - 9165

JO - Organic Letters

JF - Organic Letters

IS - 22

ER -

Regio- and Diastereoselective Copper-Catalyzed Carbometalation of Cyclopropenylsilanes

Abstract

ASJC Scopus subject areas

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