Reducing the spin-spin interaction of stable carbon radicals

Uri Green; Zeev Aizenshtat; Sharon Ruthstein; Haim Cohen

doi:10.1039/c3cp50533b

Reducing the spin-spin interaction of stable carbon radicals

Uri Green, Zeev Aizenshtat, Sharon Ruthstein, Haim Cohen

Ben-Gurion University of the Negev, Ariel University, Bar-Ilan University

Research output: Contribution to journal › Article › peer-review

Abstract

We report the discovery that a flow of CO₂, N₂ or He can sufficiently reduce the spin-spin interactions of specific stable carbon centered radicals by displacing the molecular oxygen in the atmosphere enabling their detection via electron paramagnetic resonance (EPR). This finding unlike other reported effects on carbon radicals occurs under STP conditions and is reversible.

Original language	English
Pages (from-to)	6182-6184
Number of pages	3
Journal	Physical Chemistry Chemical Physics
Volume	15
Issue number	17
DOIs	https://doi.org/10.1039/c3cp50533b
State	Published - 3 Apr 2013

All Science Journal Classification (ASJC) codes

General Physics and Astronomy
Physical and Theoretical Chemistry

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10.1039/c3cp50533b

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title = "Reducing the spin-spin interaction of stable carbon radicals",

abstract = "We report the discovery that a flow of CO2, N2 or He can sufficiently reduce the spin-spin interactions of specific stable carbon centered radicals by displacing the molecular oxygen in the atmosphere enabling their detection via electron paramagnetic resonance (EPR). This finding unlike other reported effects on carbon radicals occurs under STP conditions and is reversible.",

author = "Uri Green and Zeev Aizenshtat and Sharon Ruthstein and Haim Cohen",

year = "2013",

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doi = "10.1039/c3cp50533b",

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volume = "15",

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AU - Green, Uri

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AU - Ruthstein, Sharon

AU - Cohen, Haim

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N2 - We report the discovery that a flow of CO2, N2 or He can sufficiently reduce the spin-spin interactions of specific stable carbon centered radicals by displacing the molecular oxygen in the atmosphere enabling their detection via electron paramagnetic resonance (EPR). This finding unlike other reported effects on carbon radicals occurs under STP conditions and is reversible.

AB - We report the discovery that a flow of CO2, N2 or He can sufficiently reduce the spin-spin interactions of specific stable carbon centered radicals by displacing the molecular oxygen in the atmosphere enabling their detection via electron paramagnetic resonance (EPR). This finding unlike other reported effects on carbon radicals occurs under STP conditions and is reversible.

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U2 - 10.1039/c3cp50533b

DO - 10.1039/c3cp50533b

M3 - مقالة

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SN - 1463-9076

VL - 15

SP - 6182

EP - 6184

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

IS - 17

ER -

Reducing the spin-spin interaction of stable carbon radicals

Abstract

All Science Journal Classification (ASJC) codes

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