Realizing the potential of micro-phase separated block copolymer electrolytes: Ion domain connectivity plays a prominent role in ion conduction

C. G. Arges; Y. Kambe; M. Dolejsi; G. Wu; T. Segal-Peretz; J. Ren; P. F. Nealey

doi:10.1149/07514.1013ecst

Realizing the potential of micro-phase separated block copolymer electrolytes: Ion domain connectivity plays a prominent role in ion conduction

C. G. Arges, Y. Kambe, M. Dolejsi, G. Wu, T. Segal-Peretz, J. Ren, P. F. Nealey

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

Block copolymer electrolytes (BCEs) offer the prospect of membranes with high ionic conductivity at lower ion-exchange capacities leading to membranes with robust mechanical properties. However, the microphase separated structure of such BCE membranes and its impact on membrane conductivity is poorly understood. Most studies assume that aggregated ionic domains in microphase separated BCEs, or random copolymers, is sufficient to foster facile ion conductivity. However, microphase separation alone cannot spur rapid ion conduction. In this paper, we demonstrate that ion domain connectivity greatly influences ion conductivity in BCEs. The results emphasize the importance of maximizing ion domain connectivity while minimizing terminal defects to realize BCEs with optimal ion transport properties.

Original language	English
Title of host publication	Polymer Electrolyte Fuel Cells 16, PEFC 16
Editors	D. J. Jones, H. Uchida, H. A. Gasteiger, K. Swider-Lyons, F. N. Buchi, P. N. Pintauro, B. S. Pivovar, K. E. Ayers, K. A. Perry, P. Shirvanian, A. Z. Weber, V. K. Ramani, P. Strasser, R. A. Mantz, K. Shinohara, S. Mitsushima, C. Coutanceau, J. M. Fenton, T. J. Schmidt, T. F. Fuller, S. R. Narayanan, Y. T. Kim, L. Zhuang, S. G. Sun
Pages	1013-1020
Number of pages	8
Edition	14
ISBN (Electronic)	9781607687313, 9781607687672, 9781607687689, 9781607687696, 9781607687702, 9781607687719, 9781607687726, 9781607687733, 9781607687740, 9781607687757, 9781607687771, 9781607687788, 9781607687795, 9781607687801, 9781607687818, 9781607687825, 9781607687832, 9781607687849, 9781607687856, 9781607687863, 9781607687887, 9781607687894, 9781607687900, 9781607687917, 9781607687924, 9781607687931, 9781607687948, 9781607687955, 9781607687962, 9781607687979, 9781607687986, 9781607687993, 9781607688006, 9781607688013, 9781607688020, 9781607688037
DOIs	https://doi.org/10.1149/07514.1013ecst
State	Published - 2016
Externally published	Yes
Event	Symposium on Polymer Electrolyte Fuel Cells 16, PEFC 2016 - PRiME 2016/230th ECS Meeting - Honolulu, United States Duration: 2 Oct 2016 → 7 Oct 2016

Publication series

Name	ECS Transactions
Number	14
Volume	75

Conference

Conference	Symposium on Polymer Electrolyte Fuel Cells 16, PEFC 2016 - PRiME 2016/230th ECS Meeting
Country/Territory	United States
City	Honolulu
Period	2/10/16 → 7/10/16

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

All Science Journal Classification (ASJC) codes

General Engineering

Access to Document

10.1149/07514.1013ecst

Cite this

Arges, C. G., Kambe, Y., Dolejsi, M., Wu, G., Segal-Peretz, T., Ren, J., & Nealey, P. F. (2016). Realizing the potential of micro-phase separated block copolymer electrolytes: Ion domain connectivity plays a prominent role in ion conduction. In D. J. Jones, H. Uchida, H. A. Gasteiger, K. Swider-Lyons, F. N. Buchi, P. N. Pintauro, B. S. Pivovar, K. E. Ayers, K. A. Perry, P. Shirvanian, A. Z. Weber, V. K. Ramani, P. Strasser, R. A. Mantz, K. Shinohara, S. Mitsushima, C. Coutanceau, J. M. Fenton, T. J. Schmidt, T. F. Fuller, S. R. Narayanan, Y. T. Kim, L. Zhuang, ... S. G. Sun (Eds.), Polymer Electrolyte Fuel Cells 16, PEFC 16 (14 ed., pp. 1013-1020). (ECS Transactions; Vol. 75, No. 14). https://doi.org/10.1149/07514.1013ecst

Arges, C. G. ; Kambe, Y. ; Dolejsi, M. et al. / Realizing the potential of micro-phase separated block copolymer electrolytes : Ion domain connectivity plays a prominent role in ion conduction. Polymer Electrolyte Fuel Cells 16, PEFC 16. editor / D. J. Jones ; H. Uchida ; H. A. Gasteiger ; K. Swider-Lyons ; F. N. Buchi ; P. N. Pintauro ; B. S. Pivovar ; K. E. Ayers ; K. A. Perry ; P. Shirvanian ; A. Z. Weber ; V. K. Ramani ; P. Strasser ; R. A. Mantz ; K. Shinohara ; S. Mitsushima ; C. Coutanceau ; J. M. Fenton ; T. J. Schmidt ; T. F. Fuller ; S. R. Narayanan ; Y. T. Kim ; L. Zhuang ; S. G. Sun. 14. ed. 2016. pp. 1013-1020 (ECS Transactions; 14).

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title = "Realizing the potential of micro-phase separated block copolymer electrolytes: Ion domain connectivity plays a prominent role in ion conduction",

abstract = "Block copolymer electrolytes (BCEs) offer the prospect of membranes with high ionic conductivity at lower ion-exchange capacities leading to membranes with robust mechanical properties. However, the microphase separated structure of such BCE membranes and its impact on membrane conductivity is poorly understood. Most studies assume that aggregated ionic domains in microphase separated BCEs, or random copolymers, is sufficient to foster facile ion conductivity. However, microphase separation alone cannot spur rapid ion conduction. In this paper, we demonstrate that ion domain connectivity greatly influences ion conductivity in BCEs. The results emphasize the importance of maximizing ion domain connectivity while minimizing terminal defects to realize BCEs with optimal ion transport properties.",

author = "Arges, \{C. G.\} and Y. Kambe and M. Dolejsi and G. Wu and T. Segal-Peretz and J. Ren and Nealey, \{P. F.\}",

note = "Publisher Copyright: {\textcopyright} 2016 The Electrochemical Society.; Symposium on Polymer Electrolyte Fuel Cells 16, PEFC 2016 - PRiME 2016/230th ECS Meeting ; Conference date: 02-10-2016 Through 07-10-2016",

year = "2016",

doi = "10.1149/07514.1013ecst",

language = "الإنجليزيّة",

series = "ECS Transactions",

number = "14",

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editor = "Jones, \{D. J.\} and H. Uchida and Gasteiger, \{H. A.\} and K. Swider-Lyons and Buchi, \{F. N.\} and Pintauro, \{P. N.\} and Pivovar, \{B. S.\} and Ayers, \{K. E.\} and Perry, \{K. A.\} and P. Shirvanian and Weber, \{A. Z.\} and Ramani, \{V. K.\} and P. Strasser and Mantz, \{R. A.\} and K. Shinohara and S. Mitsushima and C. Coutanceau and Fenton, \{J. M.\} and Schmidt, \{T. J.\} and Fuller, \{T. F.\} and Narayanan, \{S. R.\} and Kim, \{Y. T.\} and L. Zhuang and Sun, \{S. G.\}",

booktitle = "Polymer Electrolyte Fuel Cells 16, PEFC 16",

edition = "14",

}

Arges, CG, Kambe, Y, Dolejsi, M, Wu, G, Segal-Peretz, T, Ren, J & Nealey, PF 2016, Realizing the potential of micro-phase separated block copolymer electrolytes: Ion domain connectivity plays a prominent role in ion conduction. in DJ Jones, H Uchida, HA Gasteiger, K Swider-Lyons, FN Buchi, PN Pintauro, BS Pivovar, KE Ayers, KA Perry, P Shirvanian, AZ Weber, VK Ramani, P Strasser, RA Mantz, K Shinohara, S Mitsushima, C Coutanceau, JM Fenton, TJ Schmidt, TF Fuller, SR Narayanan, YT Kim, L Zhuang & SG Sun (eds), Polymer Electrolyte Fuel Cells 16, PEFC 16. 14 edn, ECS Transactions, no. 14, vol. 75, pp. 1013-1020, Symposium on Polymer Electrolyte Fuel Cells 16, PEFC 2016 - PRiME 2016/230th ECS Meeting, Honolulu, United States, 2/10/16. https://doi.org/10.1149/07514.1013ecst

Realizing the potential of micro-phase separated block copolymer electrolytes: Ion domain connectivity plays a prominent role in ion conduction. / Arges, C. G.; Kambe, Y.; Dolejsi, M. et al.
Polymer Electrolyte Fuel Cells 16, PEFC 16. ed. / D. J. Jones; H. Uchida; H. A. Gasteiger; K. Swider-Lyons; F. N. Buchi; P. N. Pintauro; B. S. Pivovar; K. E. Ayers; K. A. Perry; P. Shirvanian; A. Z. Weber; V. K. Ramani; P. Strasser; R. A. Mantz; K. Shinohara; S. Mitsushima; C. Coutanceau; J. M. Fenton; T. J. Schmidt; T. F. Fuller; S. R. Narayanan; Y. T. Kim; L. Zhuang; S. G. Sun. 14. ed. 2016. p. 1013-1020 (ECS Transactions; Vol. 75, No. 14).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

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T1 - Realizing the potential of micro-phase separated block copolymer electrolytes

T2 - Symposium on Polymer Electrolyte Fuel Cells 16, PEFC 2016 - PRiME 2016/230th ECS Meeting

AU - Arges, C. G.

AU - Kambe, Y.

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AU - Segal-Peretz, T.

AU - Ren, J.

AU - Nealey, P. F.

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AB - Block copolymer electrolytes (BCEs) offer the prospect of membranes with high ionic conductivity at lower ion-exchange capacities leading to membranes with robust mechanical properties. However, the microphase separated structure of such BCE membranes and its impact on membrane conductivity is poorly understood. Most studies assume that aggregated ionic domains in microphase separated BCEs, or random copolymers, is sufficient to foster facile ion conductivity. However, microphase separation alone cannot spur rapid ion conduction. In this paper, we demonstrate that ion domain connectivity greatly influences ion conductivity in BCEs. The results emphasize the importance of maximizing ion domain connectivity while minimizing terminal defects to realize BCEs with optimal ion transport properties.

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DO - 10.1149/07514.1013ecst

M3 - منشور من مؤتمر

T3 - ECS Transactions

SP - 1013

EP - 1020

BT - Polymer Electrolyte Fuel Cells 16, PEFC 16

A2 - Jones, D. J.

A2 - Uchida, H.

A2 - Gasteiger, H. A.

A2 - Swider-Lyons, K.

A2 - Buchi, F. N.

A2 - Pintauro, P. N.

A2 - Pivovar, B. S.

A2 - Ayers, K. E.

A2 - Perry, K. A.

A2 - Shirvanian, P.

A2 - Weber, A. Z.

A2 - Ramani, V. K.

A2 - Strasser, P.

A2 - Mantz, R. A.

A2 - Shinohara, K.

A2 - Mitsushima, S.

A2 - Coutanceau, C.

A2 - Fenton, J. M.

A2 - Schmidt, T. J.

A2 - Fuller, T. F.

A2 - Narayanan, S. R.

A2 - Kim, Y. T.

A2 - Zhuang, L.

A2 - Sun, S. G.

Y2 - 2 October 2016 through 7 October 2016

ER -

Arges CG, Kambe Y, Dolejsi M, Wu G, Segal-Peretz T, Ren J et al. Realizing the potential of micro-phase separated block copolymer electrolytes: Ion domain connectivity plays a prominent role in ion conduction. In Jones DJ, Uchida H, Gasteiger HA, Swider-Lyons K, Buchi FN, Pintauro PN, Pivovar BS, Ayers KE, Perry KA, Shirvanian P, Weber AZ, Ramani VK, Strasser P, Mantz RA, Shinohara K, Mitsushima S, Coutanceau C, Fenton JM, Schmidt TJ, Fuller TF, Narayanan SR, Kim YT, Zhuang L, Sun SG, editors, Polymer Electrolyte Fuel Cells 16, PEFC 16. 14 ed. 2016. p. 1013-1020. (ECS Transactions; 14). doi: 10.1149/07514.1013ecst

Realizing the potential of micro-phase separated block copolymer electrolytes: Ion domain connectivity plays a prominent role in ion conduction

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