Reaction of ferrocenyl triselenide with tris(triphenylphosphine)platinum

I. V. Skabitskii; Yu V. Torubaev; A. A. Pasynskii

doi:https://doi.org/10.1134/S1070328415090043

Reaction of ferrocenyl triselenide with tris(triphenylphosphine)platinum

I. V. Skabitskii, Yu V. Torubaev, A. A. Pasynskii

Research output: Contribution to journal › Article › peer-review

Abstract

The reaction of ferrocenyl triselenide, Fe(C₅H₄)₂Se₃, with Pt(PPh3)₃ is accompanied by elimination of one mole of SePPh3 and gives a dimeric platinum(II) chelate complex with bridging selenium atoms, [Fe(μ-C₅H₄Se)₂Pt(PPh₃)]₂, which was characterized by X-ray diffraction (CIF file CCDC no. 1055075).

Original language	American English
Pages (from-to)	654-657
Number of pages	4
Journal	Russian Journal of Coordination Chemistry/Koordinatsionnaya Khimiya
Volume	41
Issue number	10
DOIs	https://doi.org/10.1134/S1070328415090043
State	Published - 1 Oct 2015
Externally published	Yes

All Science Journal Classification (ASJC) codes

General Chemistry
General Chemical Engineering

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title = "Reaction of ferrocenyl triselenide with tris(triphenylphosphine)platinum",

abstract = "The reaction of ferrocenyl triselenide, Fe(C5H4)2Se3, with Pt(PPh3)3 is accompanied by elimination of one mole of SePPh3 and gives a dimeric platinum(II) chelate complex with bridging selenium atoms, [Fe(μ-C5H4Se)2Pt(PPh3)]2, which was characterized by X-ray diffraction (CIF file CCDC no. 1055075).",

author = "Skabitskii, {I. V.} and Torubaev, {Yu V.} and Pasynskii, {A. A.}",

note = "Publisher Copyright: {\textcopyright} 2015 Pleiades Publishing, Ltd.",

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doi = "https://doi.org/10.1134/S1070328415090043",

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AU - Skabitskii, I. V.

AU - Torubaev, Yu V.

AU - Pasynskii, A. A.

PY - 2015/10/1

Y1 - 2015/10/1

N2 - The reaction of ferrocenyl triselenide, Fe(C5H4)2Se3, with Pt(PPh3)3 is accompanied by elimination of one mole of SePPh3 and gives a dimeric platinum(II) chelate complex with bridging selenium atoms, [Fe(μ-C5H4Se)2Pt(PPh3)]2, which was characterized by X-ray diffraction (CIF file CCDC no. 1055075).

AB - The reaction of ferrocenyl triselenide, Fe(C5H4)2Se3, with Pt(PPh3)3 is accompanied by elimination of one mole of SePPh3 and gives a dimeric platinum(II) chelate complex with bridging selenium atoms, [Fe(μ-C5H4Se)2Pt(PPh3)]2, which was characterized by X-ray diffraction (CIF file CCDC no. 1055075).

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ER -

Reaction of ferrocenyl triselenide with tris(triphenylphosphine)platinum

Abstract

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