Rapid synthesis of block and cyclic copolymers via click chemistry in the presence of copper nanoparticles

Eric D. Pressly; Roey J. Amir; Craig J. Hawker

doi:10.1002/pola.24504

Rapid synthesis of block and cyclic copolymers via click chemistry in the presence of copper nanoparticles

Eric D. Pressly, Roey J. Amir, Craig J. Hawker

Research output: Contribution to journal › Article › peer-review

Abstract

A new method for the rapid and efficient coupling of homopolymers to yield diblock and triblock copolymers as well as cyclic polymers using the 3 + 2 π Huisgen copper catalyzed cycloaddition reaction has been developed. This facile method utilizes commercially available Cu nanoparticles that are tolerant to O₂, easily removable and recyclable.

Original language	English
Pages (from-to)	814-819
Number of pages	6
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	49
Issue number	3
DOIs	https://doi.org/10.1002/pola.24504
State	Published - 1 Feb 2011
Externally published	Yes

Keywords

block copolymer
click chemistry
cyclic polymers
heterogeneous catalysis
living free radical polymerization

All Science Journal Classification (ASJC) codes

Polymers and Plastics
Organic Chemistry
Materials Chemistry

Access to Document

10.1002/pola.24504

Cite this

@article{d9bb275e05af47749e950716076078cf,

title = "Rapid synthesis of block and cyclic copolymers via click chemistry in the presence of copper nanoparticles",

abstract = "A new method for the rapid and efficient coupling of homopolymers to yield diblock and triblock copolymers as well as cyclic polymers using the 3 + 2 π Huisgen copper catalyzed cycloaddition reaction has been developed. This facile method utilizes commercially available Cu nanoparticles that are tolerant to O2, easily removable and recyclable.",

keywords = "block copolymer, click chemistry, cyclic polymers, heterogeneous catalysis, living free radical polymerization",

author = "Pressly, \{Eric D.\} and Amir, \{Roey J.\} and Hawker, \{Craig J.\}",

year = "2011",

month = feb,

day = "1",

doi = "10.1002/pola.24504",

language = "الإنجليزيّة",

volume = "49",

pages = "814--819",

journal = "Journal of Polymer Science, Part A: Polymer Chemistry",

issn = "0887-624X",

publisher = "John Wiley \& Sons Inc.",

number = "3",

}

TY - JOUR

T1 - Rapid synthesis of block and cyclic copolymers via click chemistry in the presence of copper nanoparticles

AU - Pressly, Eric D.

AU - Amir, Roey J.

AU - Hawker, Craig J.

PY - 2011/2/1

Y1 - 2011/2/1

N2 - A new method for the rapid and efficient coupling of homopolymers to yield diblock and triblock copolymers as well as cyclic polymers using the 3 + 2 π Huisgen copper catalyzed cycloaddition reaction has been developed. This facile method utilizes commercially available Cu nanoparticles that are tolerant to O2, easily removable and recyclable.

AB - A new method for the rapid and efficient coupling of homopolymers to yield diblock and triblock copolymers as well as cyclic polymers using the 3 + 2 π Huisgen copper catalyzed cycloaddition reaction has been developed. This facile method utilizes commercially available Cu nanoparticles that are tolerant to O2, easily removable and recyclable.

KW - block copolymer

KW - click chemistry

KW - cyclic polymers

KW - heterogeneous catalysis

KW - living free radical polymerization

UR - http://www.scopus.com/inward/record.url?scp=78650836598&partnerID=8YFLogxK

U2 - 10.1002/pola.24504

DO - 10.1002/pola.24504

M3 - مقالة

SN - 0887-624X

VL - 49

SP - 814

EP - 819

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

IS - 3

ER -

Rapid synthesis of block and cyclic copolymers via click chemistry in the presence of copper nanoparticles

Abstract

Keywords

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this