Abstract
We show that the second-order traps in the control landscape for a three-level Λ-system found in our previous work (Phys. Rev. Lett. 2011, 106, 120402) are not local maxima: there exist directions in the space of controls in which the objective grows. The growth of the objective is slow - at best 4th order for weak variations of the control. This implies that simple gradient methods would be problematic in the vicinity of second-order traps, where more sophisticated algorithms that exploit the higher order derivative information are necessary to climb up the control landscape efficiently. The theory is supported by a numerical investigation of the landscape in the vicinity of the ε(t)=0 second-order trap, performed using the GRAPE and BFGS algorithms.
Original language | English |
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Pages (from-to) | 467-472 |
Number of pages | 6 |
Journal | Israel Journal of Chemistry |
Volume | 52 |
Issue number | 5 |
DOIs | |
State | Published - May 2012 |
All Science Journal Classification (ASJC) codes
- General Chemistry