Preparation of methylene-substituted calixarenes

Silvio E. Biali

doi:10.1007/978-3-319-31867-7_4

Preparation of methylene-substituted calixarenes

Silvio E. Biali

Institute of Chemistry

The Hebrew University of Jerusalem

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

Abstract

The different synthetic approaches for the preparation of “classical” calixarenes with one, part, or all bridges chemically modified are reviewed. The methods include the cyclization of fragments, the homologous anionic ortho Fries rearrangement, the spirodienone method, the lithiation/alkylation approach, the oxidation of the bridges followed by reaction of the carbonyl units with organolithium reagents, and the bromination of the bridges followed by reaction with nucleophiles.

Original language	English
Title of host publication	Calixarenes and Beyond
Pages	75-93
Number of pages	19
ISBN (Electronic)	9783319318677
DOIs	https://doi.org/10.1007/978-3-319-31867-7_4
State	Published - 1 Jan 2016

Keywords

Bromination
Calixarenes
Cyclophanes
Oxidation
Synthesis

All Science Journal Classification (ASJC) codes

General Chemistry

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10.1007/978-3-319-31867-7_4

Cite this

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N2 - The different synthetic approaches for the preparation of “classical” calixarenes with one, part, or all bridges chemically modified are reviewed. The methods include the cyclization of fragments, the homologous anionic ortho Fries rearrangement, the spirodienone method, the lithiation/alkylation approach, the oxidation of the bridges followed by reaction of the carbonyl units with organolithium reagents, and the bromination of the bridges followed by reaction with nucleophiles.

AB - The different synthetic approaches for the preparation of “classical” calixarenes with one, part, or all bridges chemically modified are reviewed. The methods include the cyclization of fragments, the homologous anionic ortho Fries rearrangement, the spirodienone method, the lithiation/alkylation approach, the oxidation of the bridges followed by reaction of the carbonyl units with organolithium reagents, and the bromination of the bridges followed by reaction with nucleophiles.

KW - Bromination

KW - Calixarenes

KW - Cyclophanes

KW - Oxidation

KW - Synthesis

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BT - Calixarenes and Beyond

ER -

Preparation of methylene-substituted calixarenes

Abstract

Keywords

All Science Journal Classification (ASJC) codes

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