Practical Chemical Actinometry—A Review

Joseph Rabani; Hadas Mamane; Dana Pousty; James R. Bolton

doi:10.1111/php.13429

Practical Chemical Actinometry—A Review

Joseph Rabani
, Hadas Mamane
, Dana Pousty
, James R. Bolton

The Hebrew University of Jerusalem, Tel Aviv University

Research output: Contribution to journal › Review article › peer-review

Abstract

Actinometers are physical or chemical systems that can be employed to determine photon fluxes. Chemical actinometers are photochemical systems with known quantum yields that can be employed to determine accurate photon fluxes for specific photochemical reactions. This review explores in detail several practical chemical actinometers (ferrioxalate, iodide–iodate, uranyl oxalate, nitrate, uridine, hydrogen peroxide and several actinometers for the vacuum ultraviolet). Each actinometer is described with recommended conditions for its use.

Original language	English
Pages (from-to)	873-902
Number of pages	30
Journal	Photochemistry and Photobiology
Volume	97
Issue number	5
DOIs	https://doi.org/10.1111/php.13429
State	Published - 1 Sep 2021

ASJC Scopus subject areas

Biochemistry
General Medicine
Physical and Theoretical Chemistry

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10.1111/php.13429

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abstract = "Actinometers are physical or chemical systems that can be employed to determine photon fluxes. Chemical actinometers are photochemical systems with known quantum yields that can be employed to determine accurate photon fluxes for specific photochemical reactions. This review explores in detail several practical chemical actinometers (ferrioxalate, iodide{\textendash}iodate, uranyl oxalate, nitrate, uridine, hydrogen peroxide and several actinometers for the vacuum ultraviolet). Each actinometer is described with recommended conditions for its use.",

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AB - Actinometers are physical or chemical systems that can be employed to determine photon fluxes. Chemical actinometers are photochemical systems with known quantum yields that can be employed to determine accurate photon fluxes for specific photochemical reactions. This review explores in detail several practical chemical actinometers (ferrioxalate, iodide–iodate, uranyl oxalate, nitrate, uridine, hydrogen peroxide and several actinometers for the vacuum ultraviolet). Each actinometer is described with recommended conditions for its use.

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Practical Chemical Actinometry—A Review

Abstract

ASJC Scopus subject areas

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