Polycyclooctadiene complexes of rhodium(I): Direct access to organometallic nanoparticles

Sudheendran Mavila; Charles E. Diesendruck; Sivan Linde; Liron Amir; Rafi Shikler; N. Gabriel Lemcoff

doi:10.1002/anie.201300362

Polycyclooctadiene complexes of rhodium(I): Direct access to organometallic nanoparticles

Sudheendran Mavila
, Charles E. Diesendruck
, Sivan Linde
, Liron Amir
, Rafi Shikler
, N. Gabriel Lemcoff

Ben-Gurion University of the Negev

Research output: Contribution to journal › Article › peer-review

Abstract

Content matters: The reaction of polycyclooctadiene (Poly(COD)) and [{RhCl(C₂H₄)₂}₂] produced well-defined π-bound hybrid polymers, the size of which depended on rhodium content (see picture). The reaction of these polymers with a phosphine aldehyde led to the regeneration of the original polymers, thus proving the accessibility of the metal.

Original language	American English
Pages (from-to)	5767-5770
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	22
DOIs	https://doi.org/10.1002/anie.201300362
State	Published - 27 May 2013

Keywords

alkene ligands
macromolecular hybrids
organometallic nanoparticles
polymers
rhodium

ASJC Scopus subject areas

Catalysis
General Chemistry

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10.1002/anie.201300362

Cite this

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title = "Polycyclooctadiene complexes of rhodium(I): Direct access to organometallic nanoparticles",

abstract = "Content matters: The reaction of polycyclooctadiene (Poly(COD)) and [\{RhCl(C2H4)2\}2] produced well-defined π-bound hybrid polymers, the size of which depended on rhodium content (see picture). The reaction of these polymers with a phosphine aldehyde led to the regeneration of the original polymers, thus proving the accessibility of the metal.",

keywords = "alkene ligands, macromolecular hybrids, organometallic nanoparticles, polymers, rhodium",

author = "Sudheendran Mavila and Diesendruck, \{Charles E.\} and Sivan Linde and Liron Amir and Rafi Shikler and Lemcoff, \{N. Gabriel\}",

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T2 - Direct access to organometallic nanoparticles

AU - Mavila, Sudheendran

AU - Diesendruck, Charles E.

AU - Linde, Sivan

AU - Amir, Liron

AU - Shikler, Rafi

AU - Lemcoff, N. Gabriel

PY - 2013/5/27

Y1 - 2013/5/27

N2 - Content matters: The reaction of polycyclooctadiene (Poly(COD)) and [{RhCl(C2H4)2}2] produced well-defined π-bound hybrid polymers, the size of which depended on rhodium content (see picture). The reaction of these polymers with a phosphine aldehyde led to the regeneration of the original polymers, thus proving the accessibility of the metal.

AB - Content matters: The reaction of polycyclooctadiene (Poly(COD)) and [{RhCl(C2H4)2}2] produced well-defined π-bound hybrid polymers, the size of which depended on rhodium content (see picture). The reaction of these polymers with a phosphine aldehyde led to the regeneration of the original polymers, thus proving the accessibility of the metal.

KW - alkene ligands

KW - macromolecular hybrids

KW - organometallic nanoparticles

KW - polymers

KW - rhodium

UR - https://www.scopus.com/pages/publications/84878044103

U2 - 10.1002/anie.201300362

DO - 10.1002/anie.201300362

M3 - Article

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JF - Angewandte Chemie - International Edition

IS - 22

ER -

Polycyclooctadiene complexes of rhodium(I): Direct access to organometallic nanoparticles

Abstract

Keywords

ASJC Scopus subject areas

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