TY - JOUR
T1 - Pinching a glass reveals key properties of its soft spots
AU - Rainone, Corrado
AU - Bouchbinder, Eran
AU - Lerner, Edan
N1 - We thank David Richard for his help with our graphics. Fruitful discussions with David Richard and Geert Kapteijns are warmly acknowledged. E.B. was supported by the Minerva Foundation with funding from the Federal German Ministry for Education and Research, the Ben May Center for Chemical Theory and Computation, and the Harold Perlman Family. E.L. was supported by the Netherlands Organisation for Scientific Research (Vidi Grant 680-47-554/3259). Author contributions: C.R., E.B., and E.L. designed research; C.R. and E.L. performed research; C.R., E.B., and E.L. discussed the results; and C.R., E.B., and E.L. wrote the paper.
PY - 2020/3/10
Y1 - 2020/3/10
N2 - It is now well established that glasses feature quasilocalized nonphononic excitations—coined “soft spots”—, which follow a universal ω 4 density of states in the limit of low frequencies ω. All glass-specific properties, such as the dependence on the preparation protocol or composition, are encapsulated in the nonuniversal prefactor of the universal ω 4 law. The prefactor, however, is a composite quantity that incorporates information both about the number of quasilocalized nonphononic excitations and their characteristic stiffness, in an apparently inseparable manner. We show that by pinching a glass—i.e., by probing its response to force dipoles—one can disentangle and independently extract these two fundamental pieces of physical information. This analysis reveals that the number of quasilocalized nonphononic excitations follows a Boltzmann-like law in terms of the parent temperature from which the glass is quenched. The latter, sometimes termed the fictive (or effective) temperature, plays important roles in nonequilibrium thermodynamic approaches to the relaxation, flow, and deformation of glasses. The analysis also shows that the characteristic stiffness of quasilocalized nonphononic excitations can be related to their characteristic size, a long sought-for length scale. These results show that important physical information, which is relevant for various key questions in glass physics, can be obtained through pinching a glass.
AB - It is now well established that glasses feature quasilocalized nonphononic excitations—coined “soft spots”—, which follow a universal ω 4 density of states in the limit of low frequencies ω. All glass-specific properties, such as the dependence on the preparation protocol or composition, are encapsulated in the nonuniversal prefactor of the universal ω 4 law. The prefactor, however, is a composite quantity that incorporates information both about the number of quasilocalized nonphononic excitations and their characteristic stiffness, in an apparently inseparable manner. We show that by pinching a glass—i.e., by probing its response to force dipoles—one can disentangle and independently extract these two fundamental pieces of physical information. This analysis reveals that the number of quasilocalized nonphononic excitations follows a Boltzmann-like law in terms of the parent temperature from which the glass is quenched. The latter, sometimes termed the fictive (or effective) temperature, plays important roles in nonequilibrium thermodynamic approaches to the relaxation, flow, and deformation of glasses. The analysis also shows that the characteristic stiffness of quasilocalized nonphononic excitations can be related to their characteristic size, a long sought-for length scale. These results show that important physical information, which is relevant for various key questions in glass physics, can be obtained through pinching a glass.
UR - http://www.scopus.com/inward/record.url?scp=85081663566&partnerID=8YFLogxK
U2 - https://doi.org/10.1073/pnas.1919958117
DO - https://doi.org/10.1073/pnas.1919958117
M3 - مقالة
SN - 0027-8424
VL - 117
SP - 5228
EP - 5234
JO - Proceedings of the National Academy of Sciences of the United States of America
JF - Proceedings of the National Academy of Sciences of the United States of America
IS - 10
ER -