Phosphine and carbene azido-cations: [(L)N3]+ and [(L)2N3]+

Daniel Winkelhaus; Michael H. Holthausen; Roman Dobrovetsky; Douglas W. Stephan

doi:10.1039/c5sc02336j

Phosphine and carbene azido-cations: [(L)N₃]⁺ and [(L)₂N₃]⁺

Daniel Winkelhaus, Michael H. Holthausen, Roman Dobrovetsky, Douglas W. Stephan

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

Abstract

The cationic N₃-species [(p-HC₆F₄)₃PN₃]⁺ (1) featuring a perfluoro-arene phosphonium group serves as a N₃⁺-source in stoichiometric reactions with several Lewis bases (L) allowing for the stepwise formation of [(L)N₃]⁺ and [(L)₂N₃]⁺ cations (L = phosphine, carbene) with liberation of (p-HC₆F₄)₃P. X-Ray diffraction analysis and computational studies provide insight into the bonding in these remarkably stable azido-cations.

Original language	English
Pages (from-to)	6367-6372
Number of pages	6
Journal	Chemical Science
Volume	6
Issue number	11
DOIs	https://doi.org/10.1039/c5sc02336j
State	Published - 21 Jul 2015

All Science Journal Classification (ASJC) codes

General Chemistry

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10.1039/c5sc02336j

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title = "Phosphine and carbene azido-cations: [(L)N3]+ and [(L)2N3]+",

abstract = "The cationic N3-species [(p-HC6F4)3PN3]+ (1) featuring a perfluoro-arene phosphonium group serves as a N3+-source in stoichiometric reactions with several Lewis bases (L) allowing for the stepwise formation of [(L)N3]+ and [(L)2N3]+ cations (L = phosphine, carbene) with liberation of (p-HC6F4)3P. X-Ray diffraction analysis and computational studies provide insight into the bonding in these remarkably stable azido-cations.",

author = "Daniel Winkelhaus and Holthausen, {Michael H.} and Roman Dobrovetsky and Stephan, {Douglas W.}",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry.",

year = "2015",

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day = "21",

doi = "10.1039/c5sc02336j",

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journal = "Chemical Science",

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T1 - Phosphine and carbene azido-cations

T2 - [(L)N3]+ and [(L)2N3]+

AU - Winkelhaus, Daniel

AU - Holthausen, Michael H.

AU - Dobrovetsky, Roman

AU - Stephan, Douglas W.

PY - 2015/7/21

Y1 - 2015/7/21

N2 - The cationic N3-species [(p-HC6F4)3PN3]+ (1) featuring a perfluoro-arene phosphonium group serves as a N3+-source in stoichiometric reactions with several Lewis bases (L) allowing for the stepwise formation of [(L)N3]+ and [(L)2N3]+ cations (L = phosphine, carbene) with liberation of (p-HC6F4)3P. X-Ray diffraction analysis and computational studies provide insight into the bonding in these remarkably stable azido-cations.

AB - The cationic N3-species [(p-HC6F4)3PN3]+ (1) featuring a perfluoro-arene phosphonium group serves as a N3+-source in stoichiometric reactions with several Lewis bases (L) allowing for the stepwise formation of [(L)N3]+ and [(L)2N3]+ cations (L = phosphine, carbene) with liberation of (p-HC6F4)3P. X-Ray diffraction analysis and computational studies provide insight into the bonding in these remarkably stable azido-cations.

UR - http://www.scopus.com/inward/record.url?scp=84944077339&partnerID=8YFLogxK

U2 - 10.1039/c5sc02336j

DO - 10.1039/c5sc02336j

M3 - مقالة

C2 - 30090255

SN - 2041-6520

VL - 6

SP - 6367

EP - 6372

JO - Chemical Science

JF - Chemical Science

IS - 11

ER -

Phosphine and carbene azido-cations: [(L)N₃]⁺ and [(L)₂N₃]⁺

Abstract

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