Peculiarities of perovskite photovoltaics degradation and how to account for them in stability studies

Mark V. Khenkin; K. M. Anoop; Iris Visoly-Fisher; Francesco Di Giacomo; Ilker Dogan; Bhushan Ramesh Patil; Vida Turkovic; Morten Madsen; Yulia Galagan; Carolin Ulbrich; Eugene A. Katz

doi:10.1109/PVSC45281.2020.9300576

Peculiarities of perovskite photovoltaics degradation and how to account for them in stability studies

Mark V. Khenkin, K. M. Anoop, Iris Visoly-Fisher, Francesco Di Giacomo, Ilker Dogan, Bhushan Ramesh Patil, Vida Turkovic, Morten Madsen, Yulia Galagan, Carolin Ulbrich, Eugene A. Katz

The Swiss Institute for Dryland Environmental and Energy Research

Ben-Gurion University of the Negev

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

Abstract

Degradation of perovskite solar cells is shown to be partly reversible in the dark, which significantly affects the lifetime of the cell under operational conditions. In this contribution, complex interplay between reversible and irreversible degradation is discussed on the basis of indoor illumination-recovery experiments and outdoor exposure to natural diurnal cycle. We demonstrate that both photodegradation and subsequent recovery processes are strongly affected by the electrical bias condition during the aging. Light-induced ion migration and metastable traps formation with different dominance under different biases and at different degradation stages might explain observed features.

Original language	American English
Title of host publication	2020 47th IEEE Photovoltaic Specialists Conference, PVSC 2020
Pages	305-308
Number of pages	4
ISBN (Electronic)	9781728161150
DOIs	https://doi.org/10.1109/PVSC45281.2020.9300576
State	Published - 14 Jun 2020
Event	47th IEEE Photovoltaic Specialists Conference, PVSC 2020 - Calgary, Canada Duration: 15 Jun 2020 → 21 Aug 2020

Publication series

Name	Conference Record of the IEEE Photovoltaic Specialists Conference
Volume	2020-June

Conference

Conference	47th IEEE Photovoltaic Specialists Conference, PVSC 2020
Country/Territory	Canada
City	Calgary
Period	15/06/20 → 21/08/20

UN SDGs

This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

Keywords

electrical bias
outdoor
perovskite solar cell
recovery
stability

All Science Journal Classification (ASJC) codes

Control and Systems Engineering
Industrial and Manufacturing Engineering
Electrical and Electronic Engineering

Access to Document

10.1109/PVSC45281.2020.9300576

Cite this

Khenkin, M. V., Anoop, K. M., Visoly-Fisher, I., Di Giacomo, F., Dogan, I., Patil, B. R., Turkovic, V., Madsen, M., Galagan, Y., Ulbrich, C., & Katz, E. A. (2020). Peculiarities of perovskite photovoltaics degradation and how to account for them in stability studies. In 2020 47th IEEE Photovoltaic Specialists Conference, PVSC 2020 (pp. 305-308). Article 9300576 (Conference Record of the IEEE Photovoltaic Specialists Conference; Vol. 2020-June). https://doi.org/10.1109/PVSC45281.2020.9300576

@inproceedings{37c06bbb8c304bc19d328c03b266798c,

title = "Peculiarities of perovskite photovoltaics degradation and how to account for them in stability studies",

abstract = "Degradation of perovskite solar cells is shown to be partly reversible in the dark, which significantly affects the lifetime of the cell under operational conditions. In this contribution, complex interplay between reversible and irreversible degradation is discussed on the basis of indoor illumination-recovery experiments and outdoor exposure to natural diurnal cycle. We demonstrate that both photodegradation and subsequent recovery processes are strongly affected by the electrical bias condition during the aging. Light-induced ion migration and metastable traps formation with different dominance under different biases and at different degradation stages might explain observed features.",

keywords = "electrical bias, outdoor, perovskite solar cell, recovery, stability",

author = "Khenkin, \{Mark V.\} and Anoop, \{K. M.\} and Iris Visoly-Fisher and \{Di Giacomo\}, Francesco and Ilker Dogan and Patil, \{Bhushan Ramesh\} and Vida Turkovic and Morten Madsen and Yulia Galagan and Carolin Ulbrich and Katz, \{Eugene A.\}",

note = "Publisher Copyright: {\textcopyright} 2020 IEEE.; 47th IEEE Photovoltaic Specialists Conference, PVSC 2020 ; Conference date: 15-06-2020 Through 21-08-2020",

year = "2020",

month = jun,

day = "14",

doi = "10.1109/PVSC45281.2020.9300576",

language = "American English",

series = "Conference Record of the IEEE Photovoltaic Specialists Conference",

pages = "305--308",

booktitle = "2020 47th IEEE Photovoltaic Specialists Conference, PVSC 2020",

}

Khenkin, MV, Anoop, KM, Visoly-Fisher, I, Di Giacomo, F, Dogan, I, Patil, BR, Turkovic, V, Madsen, M, Galagan, Y, Ulbrich, C & Katz, EA 2020, Peculiarities of perovskite photovoltaics degradation and how to account for them in stability studies. in 2020 47th IEEE Photovoltaic Specialists Conference, PVSC 2020., 9300576, Conference Record of the IEEE Photovoltaic Specialists Conference, vol. 2020-June, pp. 305-308, 47th IEEE Photovoltaic Specialists Conference, PVSC 2020, Calgary, Canada, 15/06/20. https://doi.org/10.1109/PVSC45281.2020.9300576

Peculiarities of perovskite photovoltaics degradation and how to account for them in stability studies. / Khenkin, Mark V.; Anoop, K. M.; Visoly-Fisher, Iris et al.
2020 47th IEEE Photovoltaic Specialists Conference, PVSC 2020. 2020. p. 305-308 9300576 (Conference Record of the IEEE Photovoltaic Specialists Conference; Vol. 2020-June).

Research output: Chapter in Book/Report/Conference proceeding › Conference contribution › peer-review

TY - GEN

T1 - Peculiarities of perovskite photovoltaics degradation and how to account for them in stability studies

AU - Khenkin, Mark V.

AU - Anoop, K. M.

AU - Visoly-Fisher, Iris

AU - Di Giacomo, Francesco

AU - Dogan, Ilker

AU - Patil, Bhushan Ramesh

AU - Turkovic, Vida

AU - Madsen, Morten

AU - Galagan, Yulia

AU - Ulbrich, Carolin

AU - Katz, Eugene A.

PY - 2020/6/14

Y1 - 2020/6/14

N2 - Degradation of perovskite solar cells is shown to be partly reversible in the dark, which significantly affects the lifetime of the cell under operational conditions. In this contribution, complex interplay between reversible and irreversible degradation is discussed on the basis of indoor illumination-recovery experiments and outdoor exposure to natural diurnal cycle. We demonstrate that both photodegradation and subsequent recovery processes are strongly affected by the electrical bias condition during the aging. Light-induced ion migration and metastable traps formation with different dominance under different biases and at different degradation stages might explain observed features.

AB - Degradation of perovskite solar cells is shown to be partly reversible in the dark, which significantly affects the lifetime of the cell under operational conditions. In this contribution, complex interplay between reversible and irreversible degradation is discussed on the basis of indoor illumination-recovery experiments and outdoor exposure to natural diurnal cycle. We demonstrate that both photodegradation and subsequent recovery processes are strongly affected by the electrical bias condition during the aging. Light-induced ion migration and metastable traps formation with different dominance under different biases and at different degradation stages might explain observed features.

KW - electrical bias

KW - outdoor

KW - perovskite solar cell

KW - recovery

KW - stability

UR - http://www.scopus.com/inward/record.url?scp=85099532559&partnerID=8YFLogxK

U2 - 10.1109/PVSC45281.2020.9300576

DO - 10.1109/PVSC45281.2020.9300576

M3 - Conference contribution

T3 - Conference Record of the IEEE Photovoltaic Specialists Conference

SP - 305

EP - 308

BT - 2020 47th IEEE Photovoltaic Specialists Conference, PVSC 2020

T2 - 47th IEEE Photovoltaic Specialists Conference, PVSC 2020

Y2 - 15 June 2020 through 21 August 2020

ER -

Khenkin MV, Anoop KM, Visoly-Fisher I, Di Giacomo F, Dogan I, Patil BR et al. Peculiarities of perovskite photovoltaics degradation and how to account for them in stability studies. In 2020 47th IEEE Photovoltaic Specialists Conference, PVSC 2020. 2020. p. 305-308. 9300576. (Conference Record of the IEEE Photovoltaic Specialists Conference). doi: 10.1109/PVSC45281.2020.9300576

Peculiarities of perovskite photovoltaics degradation and how to account for them in stability studies

Abstract

Publication series

Conference

UN SDGs

Keywords

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this