Pd-Catalyzed Enantioselective Hydroalkynylation of Cyclopropenes

Longyang Dian; Ilan Marek

doi:https://doi.org/10.1021/acscatal.9b04960

Pd-Catalyzed Enantioselective Hydroalkynylation of Cyclopropenes

Longyang Dian, Ilan Marek

Technion - Israel Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

We report herein an easy, mild, and robust Pd-catalyzed enantioselective hydroalkynylation reaction of achiral cyclopropenes. Commercially available Pd(acac)₂ and (R)-DM-BINAP proved to be the best combination to reach high diastereo- and enantioselectivities.

Original language	English
Pages (from-to)	1289-1293
Number of pages	5
Journal	ACS Catalysis
Volume	10
Issue number	2
DOIs	https://doi.org/10.1021/acscatal.9b04960
State	Published - 26 Dec 2019

Keywords

cyclopropanes
cyclopropenes
enantioselective
hydroalkynylation
palladium

All Science Journal Classification (ASJC) codes

General Chemistry
Catalysis

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https://doi.org/10.1021/acscatal.9b04960

Cite this

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title = "Pd-Catalyzed Enantioselective Hydroalkynylation of Cyclopropenes",

abstract = "We report herein an easy, mild, and robust Pd-catalyzed enantioselective hydroalkynylation reaction of achiral cyclopropenes. Commercially available Pd(acac)2 and (R)-DM-BINAP proved to be the best combination to reach high diastereo- and enantioselectivities.",

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author = "Longyang Dian and Ilan Marek",

note = "Copyright {\textcopyright} 2019 American Chemical Society.",

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doi = "https://doi.org/10.1021/acscatal.9b04960",

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T1 - Pd-Catalyzed Enantioselective Hydroalkynylation of Cyclopropenes

AU - Dian, Longyang

AU - Marek, Ilan

PY - 2019/12/26

Y1 - 2019/12/26

N2 - We report herein an easy, mild, and robust Pd-catalyzed enantioselective hydroalkynylation reaction of achiral cyclopropenes. Commercially available Pd(acac)2 and (R)-DM-BINAP proved to be the best combination to reach high diastereo- and enantioselectivities.

AB - We report herein an easy, mild, and robust Pd-catalyzed enantioselective hydroalkynylation reaction of achiral cyclopropenes. Commercially available Pd(acac)2 and (R)-DM-BINAP proved to be the best combination to reach high diastereo- and enantioselectivities.

KW - cyclopropanes

KW - cyclopropenes

KW - enantioselective

KW - hydroalkynylation

KW - palladium

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U2 - https://doi.org/10.1021/acscatal.9b04960

DO - https://doi.org/10.1021/acscatal.9b04960

M3 - مقالة

C2 - 32953232

SN - 2155-5435

VL - 10

SP - 1289

EP - 1293

JO - ACS Catalysis

JF - ACS Catalysis

IS - 2

ER -

Pd-Catalyzed Enantioselective Hydroalkynylation of Cyclopropenes

Abstract

Keywords

All Science Journal Classification (ASJC) codes

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