Organocatalytic oxidative dimerization of alcohols to esters

Adi Abramovich; Hila Toledo; Evgeni Pisarevsky; Alex M. Szpilman

doi:10.1055/s-0032-1317018

Organocatalytic oxidative dimerization of alcohols to esters

Adi Abramovich, Hila Toledo, Evgeni Pisarevsky, Alex M. Szpilman

Technion - Israel Institute of Technology

Technion - Israel Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

2,2,6,6-Tetramethylpiperidine-1-oxyl (TEMPO) catalyzes the direct oxidation of primary alkyl alcohols to symmetric esters at 1-2mol% loadings. These rapid reactions take place at room temperature to afford the products in yields of 55-99%.

Original language	English
Pages (from-to)	2261-2265
Number of pages	5
Journal	Synlett
Volume	23
Issue number	15
DOIs	https://doi.org/10.1055/s-0032-1317018
State	Published - 2012

Keywords

alcohols
catalysis
dimerization
esters
oxidation

All Science Journal Classification (ASJC) codes

Organic Chemistry

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10.1055/s-0032-1317018

Cite this

@article{99b954af48aa4f3db8b2b231e56d9ecf,

title = "Organocatalytic oxidative dimerization of alcohols to esters",

abstract = "2,2,6,6-Tetramethylpiperidine-1-oxyl (TEMPO) catalyzes the direct oxidation of primary alkyl alcohols to symmetric esters at 1-2mol% loadings. These rapid reactions take place at room temperature to afford the products in yields of 55-99%.",

keywords = "alcohols, catalysis, dimerization, esters, oxidation",

author = "Adi Abramovich and Hila Toledo and Evgeni Pisarevsky and Szpilman, {Alex M.}",

year = "2012",

doi = "10.1055/s-0032-1317018",

language = "الإنجليزيّة",

volume = "23",

pages = "2261--2265",

journal = "Synlett",

issn = "0936-5214",

publisher = "Georg Thieme Verlag",

number = "15",

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TY - JOUR

T1 - Organocatalytic oxidative dimerization of alcohols to esters

AU - Abramovich, Adi

AU - Toledo, Hila

AU - Pisarevsky, Evgeni

AU - Szpilman, Alex M.

PY - 2012

Y1 - 2012

N2 - 2,2,6,6-Tetramethylpiperidine-1-oxyl (TEMPO) catalyzes the direct oxidation of primary alkyl alcohols to symmetric esters at 1-2mol% loadings. These rapid reactions take place at room temperature to afford the products in yields of 55-99%.

AB - 2,2,6,6-Tetramethylpiperidine-1-oxyl (TEMPO) catalyzes the direct oxidation of primary alkyl alcohols to symmetric esters at 1-2mol% loadings. These rapid reactions take place at room temperature to afford the products in yields of 55-99%.

KW - alcohols

KW - catalysis

KW - dimerization

KW - esters

KW - oxidation

UR - http://www.scopus.com/inward/record.url?scp=84865049980&partnerID=8YFLogxK

U2 - 10.1055/s-0032-1317018

DO - 10.1055/s-0032-1317018

M3 - مقالة

SN - 0936-5214

VL - 23

SP - 2261

EP - 2265

JO - Synlett

JF - Synlett

IS - 15

ER -

Organocatalytic oxidative dimerization of alcohols to esters

Abstract

Keywords

All Science Journal Classification (ASJC) codes

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