On the Phase Diagram of Calcium Carbonate Solutions

Zhaoyong Zou; Wouter J. E. M. Habraken; Luca Bertinetti; Yael Politi; Assaf Gal; Stephen Weiner; Lia Addadi; Peter Fratzl

doi:https://doi.org/10.1002/admi.201600076

On the Phase Diagram of Calcium Carbonate Solutions

Zhaoyong Zou, Wouter J. E. M. Habraken, Luca Bertinetti, Yael Politi, Assaf Gal, Stephen Weiner, Lia Addadi, Peter Fratzl

Weizmann Institute of Science

Research output: Contribution to journal › Article › peer-review

Abstract

A liquid–liquid phase boundary is experimentally determined in calcium carbonate solutions obtained by rapid mixing. Nanoparticles of amorphous calcium carbonate form at concentration higher than this boundary and their size diverges close to the boundary, which is interpreted as a spinodal line. At lower concentrations, the solution is metastable against the nucleation of crystalline calcium carbonate phases.

Original language	English
Article number	1600076
Number of pages	5
Journal	Advanced Materials Interfaces
Volume	4
Issue number	1
DOIs	https://doi.org/10.1002/admi.201600076
State	Published - 9 Jan 2017

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title = "On the Phase Diagram of Calcium Carbonate Solutions",

abstract = "A liquid–liquid phase boundary is experimentally determined in calcium carbonate solutions obtained by rapid mixing. Nanoparticles of amorphous calcium carbonate form at concentration higher than this boundary and their size diverges close to the boundary, which is interpreted as a spinodal line. At lower concentrations, the solution is metastable against the nucleation of crystalline calcium carbonate phases.",

author = "Zhaoyong Zou and Habraken, {Wouter J. E. M.} and Luca Bertinetti and Yael Politi and Assaf Gal and Stephen Weiner and Lia Addadi and Peter Fratzl",

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AU - Zou, Zhaoyong

AU - Habraken, Wouter J. E. M.

AU - Bertinetti, Luca

AU - Politi, Yael

AU - Gal, Assaf

AU - Weiner, Stephen

AU - Addadi, Lia

AU - Fratzl, Peter

PY - 2017/1/9

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N2 - A liquid–liquid phase boundary is experimentally determined in calcium carbonate solutions obtained by rapid mixing. Nanoparticles of amorphous calcium carbonate form at concentration higher than this boundary and their size diverges close to the boundary, which is interpreted as a spinodal line. At lower concentrations, the solution is metastable against the nucleation of crystalline calcium carbonate phases.

AB - A liquid–liquid phase boundary is experimentally determined in calcium carbonate solutions obtained by rapid mixing. Nanoparticles of amorphous calcium carbonate form at concentration higher than this boundary and their size diverges close to the boundary, which is interpreted as a spinodal line. At lower concentrations, the solution is metastable against the nucleation of crystalline calcium carbonate phases.

U2 - https://doi.org/10.1002/admi.201600076

DO - https://doi.org/10.1002/admi.201600076

M3 - مقالة

SN - 2196-7350

VL - 4

JO - Advanced Materials Interfaces

JF - Advanced Materials Interfaces

IS - 1

M1 - 1600076

ER -

On the Phase Diagram of Calcium Carbonate Solutions

Abstract

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