Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol

Giulia Magnabosco; Andrea M. M. Condorelli; Rose Rosenberg; Iryna Polishchuk; Boaz Pokroy; Denis Gebauer; Helmut Coelfen; Giuseppe Falini

doi:10.1039/c9cc07087g

Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol

Giulia Magnabosco, Andrea M. M. Condorelli, Rose Rosenberg, Iryna Polishchuk, Boaz Pokroy, Denis Gebauer, Helmut Coelfen, Giuseppe Falini

Technion - Israel Institute of Technology

Research output: Contribution to journal › Article › peer-review

Abstract

The effect of Mg²⁺ on the precipitation pathway of CaCO₃ in absolute ethanol has been studied to investigate the role of ion solvation in the crystallization process. Our data reveal that high concentrations of Mg²⁺ promote the precipitation of an amorphous transient phase together with non-stoichometric hydrated phases of calcium carbonate.

Original language	English
Pages (from-to)	12944-12947
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	86
DOIs	https://doi.org/10.1039/c9cc07087g
State	Published - 7 Nov 2019

All Science Journal Classification (ASJC) codes

Catalysis
Electronic, Optical and Magnetic Materials
Ceramics and Composites
General Chemistry
Surfaces, Coatings and Films
Metals and Alloys
Materials Chemistry

Access to Document

10.1039/c9cc07087g

Cite this

@article{389086e4b62b408d9cc94f681da00baf,

title = "Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol",

abstract = "The effect of Mg2+ on the precipitation pathway of CaCO3 in absolute ethanol has been studied to investigate the role of ion solvation in the crystallization process. Our data reveal that high concentrations of Mg2+ promote the precipitation of an amorphous transient phase together with non-stoichometric hydrated phases of calcium carbonate.",

author = "Giulia Magnabosco and Condorelli, {Andrea M. M.} and Rose Rosenberg and Iryna Polishchuk and Boaz Pokroy and Denis Gebauer and Helmut Coelfen and Giuseppe Falini",

note = "Publisher Copyright: This journal is {\textcopyright} The Royal Society of Chemistry.",

year = "2019",

month = nov,

day = "7",

doi = "10.1039/c9cc07087g",

language = "الإنجليزيّة",

volume = "55",

pages = "12944--12947",

number = "86",

}

TY - JOUR

T1 - Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol

AU - Magnabosco, Giulia

AU - Condorelli, Andrea M. M.

AU - Rosenberg, Rose

AU - Polishchuk, Iryna

AU - Pokroy, Boaz

AU - Gebauer, Denis

AU - Coelfen, Helmut

AU - Falini, Giuseppe

PY - 2019/11/7

Y1 - 2019/11/7

N2 - The effect of Mg2+ on the precipitation pathway of CaCO3 in absolute ethanol has been studied to investigate the role of ion solvation in the crystallization process. Our data reveal that high concentrations of Mg2+ promote the precipitation of an amorphous transient phase together with non-stoichometric hydrated phases of calcium carbonate.

AB - The effect of Mg2+ on the precipitation pathway of CaCO3 in absolute ethanol has been studied to investigate the role of ion solvation in the crystallization process. Our data reveal that high concentrations of Mg2+ promote the precipitation of an amorphous transient phase together with non-stoichometric hydrated phases of calcium carbonate.

UR - http://www.scopus.com/inward/record.url?scp=85074119130&partnerID=8YFLogxK

U2 - 10.1039/c9cc07087g

DO - 10.1039/c9cc07087g

M3 - مقالة

SN - 1359-7345

VL - 55

SP - 12944

EP - 12947

JO - Chemical Communications

JF - Chemical Communications

IS - 86

ER -

Non-stoichiometric hydrated magnesium-doped calcium carbonate precipitation in ethanol

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this