New possible mode of ligand-metal cooperation in PC(sp3)P pincer complexes

Sanaa Musa; Ronit Romm; Clarite Azerraf; Sebastian Kozuch; Dmitri Gelman

doi:10.1039/c1dt10167f

New possible mode of ligand-metal cooperation in PC(sp³)P pincer complexes

Sanaa Musa, Ronit Romm, Clarite Azerraf, Sebastian Kozuch, Dmitri Gelman

Weizmann Institute of Science, The Hebrew University of Jerusalem

Research output: Contribution to journal › Article › peer-review

Abstract

Ligand-metal cooperation in iridium and platinum complexes bearing tricyclic dibenzobarrelene-based PC(sp³)P pincer ligands is discussed. We demonstrated that the carbon-metal bond in these complexes may be efficiently cleaved and regenerated via 1,2-addition/elimination reactions.

Original language	American English
Pages (from-to)	8760-8763
Number of pages	4
Journal	Dalton Transactions
Volume	40
Issue number	35
DOIs	https://doi.org/10.1039/c1dt10167f
State	Published - 21 Sep 2011

All Science Journal Classification (ASJC) codes

Inorganic Chemistry

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10.1039/c1dt10167f

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title = "New possible mode of ligand-metal cooperation in PC(sp3)P pincer complexes",

abstract = "Ligand-metal cooperation in iridium and platinum complexes bearing tricyclic dibenzobarrelene-based PC(sp3)P pincer ligands is discussed. We demonstrated that the carbon-metal bond in these complexes may be efficiently cleaved and regenerated via 1,2-addition/elimination reactions.",

author = "Sanaa Musa and Ronit Romm and Clarite Azerraf and Sebastian Kozuch and Dmitri Gelman",

note = "Israeli Science FoundationSM and RR contributed equally to this paper. SK performed theoretical studies. DG thanks Israeli Science Foundation for financial support. We also thank Dr Shmuel Cohen for solving X-ray structures.",

year = "2011",

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doi = "10.1039/c1dt10167f",

language = "American English",

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AU - Musa, Sanaa

AU - Romm, Ronit

AU - Azerraf, Clarite

AU - Kozuch, Sebastian

AU - Gelman, Dmitri

N1 - Israeli Science FoundationSM and RR contributed equally to this paper. SK performed theoretical studies. DG thanks Israeli Science Foundation for financial support. We also thank Dr Shmuel Cohen for solving X-ray structures.

PY - 2011/9/21

Y1 - 2011/9/21

N2 - Ligand-metal cooperation in iridium and platinum complexes bearing tricyclic dibenzobarrelene-based PC(sp3)P pincer ligands is discussed. We demonstrated that the carbon-metal bond in these complexes may be efficiently cleaved and regenerated via 1,2-addition/elimination reactions.

AB - Ligand-metal cooperation in iridium and platinum complexes bearing tricyclic dibenzobarrelene-based PC(sp3)P pincer ligands is discussed. We demonstrated that the carbon-metal bond in these complexes may be efficiently cleaved and regenerated via 1,2-addition/elimination reactions.

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U2 - 10.1039/c1dt10167f

DO - 10.1039/c1dt10167f

M3 - Article

C2 - 21431178

SN - 1477-9226

VL - 40

SP - 8760

EP - 8763

JO - Dalton Transactions

JF - Dalton Transactions

IS - 35

ER -

New possible mode of ligand-metal cooperation in PC(sp³)P pincer complexes

Abstract

All Science Journal Classification (ASJC) codes

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