TY - JOUR
T1 - Multi-dimensional wavepacket and potential reconstruction by resonant coherent anti-Stokes Raman scattering
T2 - Application to H 2O and HOD
AU - Avisar, David
AU - Tannor, David
N1 - Minerva FoundationThis research was supported by the Minerva Foundation. This research is made possible by the historic generosity of the Harold Perlman family.
PY - 2012/6/7
Y1 - 2012/6/7
N2 - We have recently proposed a methodology for reconstructing excited-state (ExS) molecular wavepackets, and the corresponding potential energy surface, from three-pulse resonant coherent anti-Stokes Raman scattering and knowledge of the ground-state potential [Avisar and Tannor, Phys. Rev. Lett. 106, 170405 (2011)10.1103/PhysRevLett.106.170405]. The methodology is general for polyatomics and applies to any form of ExS potential - bound or dissociative. In our previous work we demonstrated the method on diatomics. Here, we demonstrate the method on the triatomics H 2O and HOD, reconstructing the ExS wavepacket and potential in the two bond-stretching coordinates.
AB - We have recently proposed a methodology for reconstructing excited-state (ExS) molecular wavepackets, and the corresponding potential energy surface, from three-pulse resonant coherent anti-Stokes Raman scattering and knowledge of the ground-state potential [Avisar and Tannor, Phys. Rev. Lett. 106, 170405 (2011)10.1103/PhysRevLett.106.170405]. The methodology is general for polyatomics and applies to any form of ExS potential - bound or dissociative. In our previous work we demonstrated the method on diatomics. Here, we demonstrate the method on the triatomics H 2O and HOD, reconstructing the ExS wavepacket and potential in the two bond-stretching coordinates.
UR - http://www.scopus.com/inward/record.url?scp=84862547501&partnerID=8YFLogxK
U2 - https://doi.org/10.1063/1.4722648
DO - https://doi.org/10.1063/1.4722648
M3 - مقالة
SN - 0021-9606
VL - 136
JO - Journal of Chemical Physics
JF - Journal of Chemical Physics
IS - 21
M1 - 214107
ER -