Ligand-metal cooperating PC(sp3)P pincer complexes as catalysts in olefin hydroformylation

Sanaa Musa; Oleg A. Filippov; Natalia V. Belkova; Elena S. Shubina; Gleb A. Silantyev; Lutz Ackermann; Dmitri Gelman

doi:10.1002/chem.201303311

Ligand-metal cooperating PC(sp³)P pincer complexes as catalysts in olefin hydroformylation

Sanaa Musa, Oleg A. Filippov, Natalia V. Belkova, Elena S. Shubina, Gleb A. Silantyev, Lutz Ackermann, Dmitri Gelman

Institute of Chemistry

The Hebrew University of Jerusalem

Research output: Contribution to journal › Article › peer-review

Abstract

Ligand-metal cooperation: A new ligand-metal cooperating catalyst for the hydroformylation of olefins is described (see scheme). The mechanism of the H₂ activation and C-H bond formation of the catalyst involves an intramolecular cooperation between the structurally remote functionality and the metal center and proceeds without change of the oxidation state of the metal.

Original language	English
Pages (from-to)	16906-16909
Number of pages	4
Journal	Chemistry - A European Journal
Volume	19
Issue number	50
DOIs	https://doi.org/10.1002/chem.201303311
State	Published - 9 Dec 2013

Keywords

catalysis
hydroformylation
ligand-metal cooperation
noninnocent ligands
pincer complexes

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Organic Chemistry

Access to Document

10.1002/chem.201303311

Cite this

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title = "Ligand-metal cooperating PC(sp3)P pincer complexes as catalysts in olefin hydroformylation",

abstract = "Ligand-metal cooperation: A new ligand-metal cooperating catalyst for the hydroformylation of olefins is described (see scheme). The mechanism of the H2 activation and C-H bond formation of the catalyst involves an intramolecular cooperation between the structurally remote functionality and the metal center and proceeds without change of the oxidation state of the metal.",

keywords = "catalysis, hydroformylation, ligand-metal cooperation, noninnocent ligands, pincer complexes",

author = "Sanaa Musa and Filippov, \{Oleg A.\} and Belkova, \{Natalia V.\} and Shubina, \{Elena S.\} and Silantyev, \{Gleb A.\} and Lutz Ackermann and Dmitri Gelman",

year = "2013",

month = dec,

day = "9",

doi = "10.1002/chem.201303311",

language = "الإنجليزيّة",

volume = "19",

pages = "16906--16909",

journal = "Chemistry - A European Journal",

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TY - JOUR

T1 - Ligand-metal cooperating PC(sp3)P pincer complexes as catalysts in olefin hydroformylation

AU - Musa, Sanaa

AU - Filippov, Oleg A.

AU - Belkova, Natalia V.

AU - Shubina, Elena S.

AU - Silantyev, Gleb A.

AU - Ackermann, Lutz

AU - Gelman, Dmitri

PY - 2013/12/9

Y1 - 2013/12/9

N2 - Ligand-metal cooperation: A new ligand-metal cooperating catalyst for the hydroformylation of olefins is described (see scheme). The mechanism of the H2 activation and C-H bond formation of the catalyst involves an intramolecular cooperation between the structurally remote functionality and the metal center and proceeds without change of the oxidation state of the metal.

AB - Ligand-metal cooperation: A new ligand-metal cooperating catalyst for the hydroformylation of olefins is described (see scheme). The mechanism of the H2 activation and C-H bond formation of the catalyst involves an intramolecular cooperation between the structurally remote functionality and the metal center and proceeds without change of the oxidation state of the metal.

KW - catalysis

KW - hydroformylation

KW - ligand-metal cooperation

KW - noninnocent ligands

KW - pincer complexes

UR - http://www.scopus.com/inward/record.url?scp=84889606684&partnerID=8YFLogxK

U2 - 10.1002/chem.201303311

DO - 10.1002/chem.201303311

M3 - مقالة

SN - 0947-6539

VL - 19

SP - 16906

EP - 16909

JO - Chemistry - A European Journal

JF - Chemistry - A European Journal

IS - 50

ER -