Isolable cyclic (alkyl)(amino)carbene-phosphonyl radical adducts

Yulia Livshits-Kritsman; Boris Tumanskii; Gabriel Ménard; Roman Dobrovetsky

doi:https://doi.org/10.1039/c9cc09244g

Isolable cyclic (alkyl)(amino)carbene-phosphonyl radical adducts

Yulia Livshits-Kritsman, Boris Tumanskii, Gabriel Ménard, Roman Dobrovetsky

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

Abstract

Phosphonyl radicals ([R₂PO]) and their adducts are proposed as intermediates in a number of important chemical and biological processes. Despite the great interest in these species, there are no examples of stable, isolated phosphonyl radicals or their adducts reported in the literature. Here we report the synthesis, EPR and theoretical study of stable, isolable cyclic (alkyl)(amino)carbene (cAAC)-phosphonyl radical adducts, [cAAC-P(O)R₂] (R = OPrⁱ, Ph).

Original language	English
Pages (from-to)	1341-1344
Number of pages	4
Journal	Chemical Communications
Volume	56
Issue number	9
DOIs	https://doi.org/10.1039/c9cc09244g
State	Published - 2020

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
General Chemistry
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Catalysis

Access to Document

https://doi.org/10.1039/c9cc09244g

Cite this

@article{49de271e3da144c7b15ad50d27b61502,

title = "Isolable cyclic (alkyl)(amino)carbene-phosphonyl radical adducts",

abstract = "Phosphonyl radicals ([R2PO]) and their adducts are proposed as intermediates in a number of important chemical and biological processes. Despite the great interest in these species, there are no examples of stable, isolated phosphonyl radicals or their adducts reported in the literature. Here we report the synthesis, EPR and theoretical study of stable, isolable cyclic (alkyl)(amino)carbene (cAAC)-phosphonyl radical adducts, [cAAC-P(O)R2] (R = OPri, Ph).",

author = "Yulia Livshits-Kritsman and Boris Tumanskii and Gabriel M{\'e}nard and Roman Dobrovetsky",

note = "Publisher Copyright: This journal is {\textcopyright} The Royal Society of Chemistry.",

year = "2020",

doi = "https://doi.org/10.1039/c9cc09244g",

language = "الإنجليزيّة",

volume = "56",

pages = "1341--1344",

number = "9",

}

TY - JOUR

T1 - Isolable cyclic (alkyl)(amino)carbene-phosphonyl radical adducts

AU - Livshits-Kritsman, Yulia

AU - Tumanskii, Boris

AU - Ménard, Gabriel

AU - Dobrovetsky, Roman

N1 - Publisher Copyright: This journal is © The Royal Society of Chemistry.

PY - 2020

Y1 - 2020

N2 - Phosphonyl radicals ([R2PO]) and their adducts are proposed as intermediates in a number of important chemical and biological processes. Despite the great interest in these species, there are no examples of stable, isolated phosphonyl radicals or their adducts reported in the literature. Here we report the synthesis, EPR and theoretical study of stable, isolable cyclic (alkyl)(amino)carbene (cAAC)-phosphonyl radical adducts, [cAAC-P(O)R2] (R = OPri, Ph).

AB - Phosphonyl radicals ([R2PO]) and their adducts are proposed as intermediates in a number of important chemical and biological processes. Despite the great interest in these species, there are no examples of stable, isolated phosphonyl radicals or their adducts reported in the literature. Here we report the synthesis, EPR and theoretical study of stable, isolable cyclic (alkyl)(amino)carbene (cAAC)-phosphonyl radical adducts, [cAAC-P(O)R2] (R = OPri, Ph).

UR - http://www.scopus.com/inward/record.url?scp=85078692425&partnerID=8YFLogxK

U2 - https://doi.org/10.1039/c9cc09244g

DO - https://doi.org/10.1039/c9cc09244g

M3 - مقالة

C2 - 31912813

SN - 1359-7345

VL - 56

SP - 1341

EP - 1344

JO - Chemical Communications

JF - Chemical Communications

IS - 9

ER -

Isolable cyclic (alkyl)(amino)carbene-phosphonyl radical adducts

Abstract

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this