Iron chemistry of an asymmetrically substituted, triazole-functionalised calixarene ligand

Michaela Ritter; Anat Molad; Varun Rawat; Arkadi Vigalok; Christian Limberg

doi:10.1080/10610278.2013.868896

Iron chemistry of an asymmetrically substituted, triazole-functionalised calixarene ligand

Michaela Ritter
, Anat Molad
, Varun Rawat
, Arkadi Vigalok
, Christian Limberg

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

Abstract

The synthesis and characterisation of an asymmetrically substituted calix-triazole ligand are reported. The ligand reacts with the Fe(II) precursor Fe₂Mes₄ to yield an iron(II) calixarene complex that is oxidised by dioxygen to provide a dinuclear Fe(III) compound featuring an oxido bridge.

Original language	English
Pages (from-to)	530-537
Number of pages	8
Journal	Supramolecular Chemistry
Volume	26
Issue number	7-8
DOIs	https://doi.org/10.1080/10610278.2013.868896
State	Published - 3 Aug 2014

Keywords

calixarene
cross-coupling
metal complexes
triazole

ASJC Scopus subject areas

General Chemistry

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10.1080/10610278.2013.868896

Cite this

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title = "Iron chemistry of an asymmetrically substituted, triazole-functionalised calixarene ligand",

abstract = "The synthesis and characterisation of an asymmetrically substituted calix-triazole ligand are reported. The ligand reacts with the Fe(II) precursor Fe2Mes4 to yield an iron(II) calixarene complex that is oxidised by dioxygen to provide a dinuclear Fe(III) compound featuring an oxido bridge.",

keywords = "calixarene, cross-coupling, metal complexes, triazole",

author = "Michaela Ritter and Anat Molad and Varun Rawat and Arkadi Vigalok and Christian Limberg",

note = "Funding Information: This research was supported by a Grant from the GIF, the German-Israeli Foundation for Scientific Research and Development. We are grateful to Dr. Beatrice Braun for performing the crystal structure analyses.",

year = "2014",

month = aug,

day = "3",

doi = "10.1080/10610278.2013.868896",

language = "الإنجليزيّة",

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journal = "Supramolecular Chemistry",

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TY - JOUR

T1 - Iron chemistry of an asymmetrically substituted, triazole-functionalised calixarene ligand

AU - Ritter, Michaela

AU - Molad, Anat

AU - Rawat, Varun

AU - Vigalok, Arkadi

AU - Limberg, Christian

N1 - Funding Information: This research was supported by a Grant from the GIF, the German-Israeli Foundation for Scientific Research and Development. We are grateful to Dr. Beatrice Braun for performing the crystal structure analyses.

PY - 2014/8/3

Y1 - 2014/8/3

N2 - The synthesis and characterisation of an asymmetrically substituted calix-triazole ligand are reported. The ligand reacts with the Fe(II) precursor Fe2Mes4 to yield an iron(II) calixarene complex that is oxidised by dioxygen to provide a dinuclear Fe(III) compound featuring an oxido bridge.

AB - The synthesis and characterisation of an asymmetrically substituted calix-triazole ligand are reported. The ligand reacts with the Fe(II) precursor Fe2Mes4 to yield an iron(II) calixarene complex that is oxidised by dioxygen to provide a dinuclear Fe(III) compound featuring an oxido bridge.

KW - calixarene

KW - cross-coupling

KW - metal complexes

KW - triazole

UR - https://www.scopus.com/pages/publications/84903306431

U2 - 10.1080/10610278.2013.868896

DO - 10.1080/10610278.2013.868896

M3 - مقالة

SN - 1061-0278

VL - 26

SP - 530

EP - 537

JO - Supramolecular Chemistry

JF - Supramolecular Chemistry

IS - 7-8

ER -

Iron chemistry of an asymmetrically substituted, triazole-functionalised calixarene ligand

Abstract

Keywords

ASJC Scopus subject areas

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