Interfacial halogen bonding probed using force spectroscopy

Meital Boterashvili; Tanya Shirman; Sidney Cohen; Guennadi Evmenenko; Pulak Dutta; Petr Milko; Gregory Leitus; Michal Lahav; Milko E. van der Boom

doi:10.1039/c3cc40378e

Interfacial halogen bonding probed using force spectroscopy

Meital Boterashvili, Tanya Shirman, Sidney Cohen, Guennadi Evmenenko, Pulak Dutta, Petr Milko, Gregory Leitus, Michal Lahav, Milko E. van der Boom

Weizmann Institute of Science

Research output: Contribution to journal › Article › peer-review

Abstract

Halogen bonding between complementary organic monolayers was directly observed in an organic environment using force spectroscopy. This non-covalent interaction is significantly affected by the nature of the organic media. We also demonstrated the effect of lateral packing interactions on the optical properties of the monolayers.x

Original language	English
Pages (from-to)	3531-3533
Number of pages	3
Journal	Chemical Communications
Volume	49
Issue number	34
DOIs	https://doi.org/10.1039/c3cc40378e
State	Published - 2 Apr 2013

All Science Journal Classification (ASJC) codes

Electronic, Optical and Magnetic Materials
General Chemistry
Ceramics and Composites
Metals and Alloys
Materials Chemistry
Surfaces, Coatings and Films
Catalysis

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10.1039/c3cc40378e

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title = "Interfacial halogen bonding probed using force spectroscopy",

abstract = "Halogen bonding between complementary organic monolayers was directly observed in an organic environment using force spectroscopy. This non-covalent interaction is significantly affected by the nature of the organic media. We also demonstrated the effect of lateral packing interactions on the optical properties of the monolayers.x",

author = "Meital Boterashvili and Tanya Shirman and Sidney Cohen and Guennadi Evmenenko and Pulak Dutta and Petr Milko and Gregory Leitus and Michal Lahav and {van der Boom}, {Milko E.}",

note = "Kimmel Center for Molecular Design; U.S. National Science Foundation [DMR-1006432]; Martin Kushner Schnur (Mexico); Aboud and Amy Dweck (Rockville, MD); U.S. Department of Energy [DE-AC02-98CH10886]This research was supported by the Kimmel Center for Molecular Design, the U.S. National Science Foundation (DMR-1006432), Martin Kushner Schnur (Mexico), and Aboud and Amy Dweck (Rockville, MD). The X-ray reflectivity measurements were performed at Beamlines X6B and X18A of the National Synchrotron Light Source, supported by the U.S. Department of Energy (DE-AC02-98CH10886). XPS measurements were performed by Dr Hagai Cohen and Dr Tatyana Bendikov (WIS). We thank Dr Mark A. Iron (WIS) for fruitful discussions. MB is the Incumbent of the Bruce A. Pearlman Professorial Chair in Synthetic Organic Chemistry.",

year = "2013",

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day = "2",

doi = "10.1039/c3cc40378e",

language = "الإنجليزيّة",

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TY - JOUR

T1 - Interfacial halogen bonding probed using force spectroscopy

AU - Boterashvili, Meital

AU - Shirman, Tanya

AU - Cohen, Sidney

AU - Evmenenko, Guennadi

AU - Dutta, Pulak

AU - Milko, Petr

AU - Leitus, Gregory

AU - Lahav, Michal

AU - van der Boom, Milko E.

N1 - Kimmel Center for Molecular Design; U.S. National Science Foundation [DMR-1006432]; Martin Kushner Schnur (Mexico); Aboud and Amy Dweck (Rockville, MD); U.S. Department of Energy [DE-AC02-98CH10886]This research was supported by the Kimmel Center for Molecular Design, the U.S. National Science Foundation (DMR-1006432), Martin Kushner Schnur (Mexico), and Aboud and Amy Dweck (Rockville, MD). The X-ray reflectivity measurements were performed at Beamlines X6B and X18A of the National Synchrotron Light Source, supported by the U.S. Department of Energy (DE-AC02-98CH10886). XPS measurements were performed by Dr Hagai Cohen and Dr Tatyana Bendikov (WIS). We thank Dr Mark A. Iron (WIS) for fruitful discussions. MB is the Incumbent of the Bruce A. Pearlman Professorial Chair in Synthetic Organic Chemistry.

PY - 2013/4/2

Y1 - 2013/4/2

N2 - Halogen bonding between complementary organic monolayers was directly observed in an organic environment using force spectroscopy. This non-covalent interaction is significantly affected by the nature of the organic media. We also demonstrated the effect of lateral packing interactions on the optical properties of the monolayers.x

AB - Halogen bonding between complementary organic monolayers was directly observed in an organic environment using force spectroscopy. This non-covalent interaction is significantly affected by the nature of the organic media. We also demonstrated the effect of lateral packing interactions on the optical properties of the monolayers.x

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U2 - 10.1039/c3cc40378e

DO - 10.1039/c3cc40378e

M3 - مقالة

SN - 1359-7345

VL - 49

SP - 3531

EP - 3533

JO - Chemical Communications

JF - Chemical Communications

IS - 34

ER -

Interfacial halogen bonding probed using force spectroscopy

Abstract

All Science Journal Classification (ASJC) codes

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