Interface engineering for high-performance, triple-halide perovskite–silicon tandem solar cells

Silvia Mariotti; Eike Köhnen; Florian Scheler; Kári Sveinbjörnsson; Lea Zimmermann; Manuel Piot; Fengjiu Yang; Bor Li; Jonathan Warby; Artem Musiienko; Dorothee Menzel; Felix Lang; Sebastian Keßler; Igal Levine; Daniele Mantione; Amran Al-Ashouri; Marlene S. Härtel; Ke Xu; Alexandros Cruz; Jona Kurpiers; Philipp Wagner; Hans Köbler; Jinzhao Li; Artiom Magomedov; David Mecerreyes; Eva Unger; Antonio Abate; Martin Stolterfoht; Bernd Stannowski; Rutger Schlatmann; Lars Korte; Steve Albrecht

doi:10.1126/science.adf5872

Interface engineering for high-performance, triple-halide perovskite–silicon tandem solar cells

Silvia Mariotti, Eike Köhnen, Florian Scheler, Kári Sveinbjörnsson, Lea Zimmermann, Manuel Piot, Fengjiu Yang, Bor Li, Jonathan Warby, Artem Musiienko, Dorothee Menzel, Felix Lang, Sebastian Keßler, Igal Levine, Daniele Mantione, Amran Al-Ashouri, Marlene S. Härtel, Ke Xu, Alexandros Cruz, Jona KurpiersPhilipp Wagner, Hans Köbler, Jinzhao Li, Artiom Magomedov, David Mecerreyes, Eva Unger, Antonio Abate, Martin Stolterfoht, Bernd Stannowski, Rutger Schlatmann, Lars Korte, Steve Albrecht

Research output: Contribution to journal › Article › peer-review

Abstract

Improved stability and efficiency of two-terminal monolithic perovskite-silicon tandem solar cells will require reductions in recombination losses. By combining a triple-halide perovskite (1.68 electron volt bandgap) with a piperazinium iodide interfacial modification, we improved the band alignment, reduced nonradiative recombination losses, and enhanced charge extraction at the electron-selective contact. Solar cells showed open-circuit voltages of up to 1.28 volts in p-i-n single junctions and 2.00 volts in perovskite-silicon tandem solar cells. The tandem cells achieve certified power conversion efficiencies of up to 32.5%.

Original language	English
Pages (from-to)	63-69
Number of pages	7
Journal	Science
Volume	381
Issue number	6653
DOIs	https://doi.org/10.1126/science.adf5872
State	Published - 1 Jul 2023
Externally published	Yes

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This output contributes to the following UN Sustainable Development Goals (SDGs)

SDG 7 Affordable and Clean Energy

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Cite this

Mariotti, S., Köhnen, E., Scheler, F., Sveinbjörnsson, K., Zimmermann, L., Piot, M., Yang, F., Li, B., Warby, J., Musiienko, A., Menzel, D., Lang, F., Keßler, S., Levine, I., Mantione, D., Al-Ashouri, A., Härtel, M. S., Xu, K., Cruz, A., ... Albrecht, S. (2023). Interface engineering for high-performance, triple-halide perovskite–silicon tandem solar cells. Science, 381(6653), 63-69. https://doi.org/10.1126/science.adf5872

@article{297777ca761e4614a99e6fff4b834cb3,

title = "Interface engineering for high-performance, triple-halide perovskite–silicon tandem solar cells",

abstract = "Improved stability and efficiency of two-terminal monolithic perovskite-silicon tandem solar cells will require reductions in recombination losses. By combining a triple-halide perovskite (1.68 electron volt bandgap) with a piperazinium iodide interfacial modification, we improved the band alignment, reduced nonradiative recombination losses, and enhanced charge extraction at the electron-selective contact. Solar cells showed open-circuit voltages of up to 1.28 volts in p-i-n single junctions and 2.00 volts in perovskite-silicon tandem solar cells. The tandem cells achieve certified power conversion efficiencies of up to 32.5%.",

author = "Silvia Mariotti and Eike K{\"o}hnen and Florian Scheler and K{\'a}ri Sveinbj{\"o}rnsson and Lea Zimmermann and Manuel Piot and Fengjiu Yang and Bor Li and Jonathan Warby and Artem Musiienko and Dorothee Menzel and Felix Lang and Sebastian Ke{\ss}ler and Igal Levine and Daniele Mantione and Amran Al-Ashouri and H{\"a}rtel, {Marlene S.} and Ke Xu and Alexandros Cruz and Jona Kurpiers and Philipp Wagner and Hans K{\"o}bler and Jinzhao Li and Artiom Magomedov and David Mecerreyes and Eva Unger and Antonio Abate and Martin Stolterfoht and Bernd Stannowski and Rutger Schlatmann and Lars Korte and Steve Albrecht",

year = "2023",

month = jul,

day = "1",

doi = "10.1126/science.adf5872",

language = "الإنجليزيّة",

volume = "381",

pages = "63--69",

journal = "Science",

issn = "0036-8075",

publisher = "American Association for the Advancement of Science",

number = "6653",

}

Mariotti, S, Köhnen, E, Scheler, F, Sveinbjörnsson, K, Zimmermann, L, Piot, M, Yang, F, Li, B, Warby, J, Musiienko, A, Menzel, D, Lang, F, Keßler, S, Levine, I, Mantione, D, Al-Ashouri, A, Härtel, MS, Xu, K, Cruz, A, Kurpiers, J, Wagner, P, Köbler, H, Li, J, Magomedov, A, Mecerreyes, D, Unger, E, Abate, A, Stolterfoht, M, Stannowski, B, Schlatmann, R, Korte, L & Albrecht, S 2023, 'Interface engineering for high-performance, triple-halide perovskite–silicon tandem solar cells', Science, vol. 381, no. 6653, pp. 63-69. https://doi.org/10.1126/science.adf5872

TY - JOUR

T1 - Interface engineering for high-performance, triple-halide perovskite–silicon tandem solar cells

AU - Mariotti, Silvia

AU - Köhnen, Eike

AU - Scheler, Florian

AU - Sveinbjörnsson, Kári

AU - Zimmermann, Lea

AU - Piot, Manuel

AU - Yang, Fengjiu

AU - Li, Bor

AU - Warby, Jonathan

AU - Musiienko, Artem

AU - Menzel, Dorothee

AU - Lang, Felix

AU - Keßler, Sebastian

AU - Levine, Igal

AU - Mantione, Daniele

AU - Al-Ashouri, Amran

AU - Härtel, Marlene S.

AU - Xu, Ke

AU - Cruz, Alexandros

AU - Kurpiers, Jona

AU - Wagner, Philipp

AU - Köbler, Hans

AU - Li, Jinzhao

AU - Magomedov, Artiom

AU - Mecerreyes, David

AU - Unger, Eva

AU - Abate, Antonio

AU - Stolterfoht, Martin

AU - Stannowski, Bernd

AU - Schlatmann, Rutger

AU - Korte, Lars

AU - Albrecht, Steve

PY - 2023/7/1

Y1 - 2023/7/1

N2 - Improved stability and efficiency of two-terminal monolithic perovskite-silicon tandem solar cells will require reductions in recombination losses. By combining a triple-halide perovskite (1.68 electron volt bandgap) with a piperazinium iodide interfacial modification, we improved the band alignment, reduced nonradiative recombination losses, and enhanced charge extraction at the electron-selective contact. Solar cells showed open-circuit voltages of up to 1.28 volts in p-i-n single junctions and 2.00 volts in perovskite-silicon tandem solar cells. The tandem cells achieve certified power conversion efficiencies of up to 32.5%.

AB - Improved stability and efficiency of two-terminal monolithic perovskite-silicon tandem solar cells will require reductions in recombination losses. By combining a triple-halide perovskite (1.68 electron volt bandgap) with a piperazinium iodide interfacial modification, we improved the band alignment, reduced nonradiative recombination losses, and enhanced charge extraction at the electron-selective contact. Solar cells showed open-circuit voltages of up to 1.28 volts in p-i-n single junctions and 2.00 volts in perovskite-silicon tandem solar cells. The tandem cells achieve certified power conversion efficiencies of up to 32.5%.

UR - http://www.scopus.com/inward/record.url?scp=85164274162&partnerID=8YFLogxK

U2 - 10.1126/science.adf5872

DO - 10.1126/science.adf5872

M3 - مقالة

C2 - 37410849

SN - 0036-8075

VL - 381

SP - 63

EP - 69

JO - Science

JF - Science

IS - 6653

ER -

Interface engineering for high-performance, triple-halide perovskite–silicon tandem solar cells

Abstract

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