Inchworm Monte Carlo for exact non-adiabatic dynamics. II. Benchmarks and comparison with established methods

Hsing Ta Chen, Guy Cohen, David R. Reichman

Research output: Contribution to journalArticlepeer-review

Abstract

In this second paper of a two part series, we present extensive benchmark results for two different inchworm Monte Carlo expansions for the spin-boson model. Our results are compared to previously developed numerically exact approaches for this problem. A detailed discussion of convergence and error propagation is presented. Our results and analysis allow for an understanding of the benefits and drawbacks of inchworm Monte Carlo compared to other approaches for exact real-time non-adiabatic quantum dynamics.

Original languageEnglish
Article number054106
JournalJournal of Chemical Physics
Volume146
Issue number5
DOIs
StatePublished - 7 Feb 2017

All Science Journal Classification (ASJC) codes

  • General Physics and Astronomy
  • Physical and Theoretical Chemistry

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