Hydrogen Peroxide Insular Dodecameric and Pentameric Clusters in Peroxosolvate Structures

Dmitry A. Grishanov; Mger A. Navasardyan; Alexander G. Medvedev; Ovadia Lev; Petr V. Prikhodchenko; Andrei V. Churakov

doi:10.1002/anie.201709699

Hydrogen Peroxide Insular Dodecameric and Pentameric Clusters in Peroxosolvate Structures

Dmitry A. Grishanov, Mger A. Navasardyan, Alexander G. Medvedev, Ovadia Lev, Petr V. Prikhodchenko, Andrei V. Churakov

Institute of Chemistry

The Hebrew University of Jerusalem

Research output: Contribution to journal › Article › peer-review

Abstract

Peroxosolvates of 2-aminonicotinic acid (I) and lidocaine N-oxide (II) including the largest insular hydrogen peroxide clusters were isolated and their crystal structures were determined by single-crystal X-ray diffraction. An unprecedented dodecameric hydrogen peroxide insular cluster was found in I. An unusual cross-like pentameric cluster was observed in the structure of II. The topology of the (H₂O₂)₁₂ assembly was never observed for small-molecule clusters. In I and II new double and triple cross-orientational disorders of H₂O₂ were found. Cluster II is the first example of a peroxosolvate crystal structure containing H₂O₂ molecules with a homoleptic hydrogen peroxide environment. In II, a hydrogen bond between an H₂O₂ molecule and a peptide group -CONH⋅⋅⋅O₂H₂ was observed for the first time.

Original language	English
Pages (from-to)	15241-15245
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	56
Issue number	48
DOIs	https://doi.org/10.1002/anie.201709699
State	Published - 27 Nov 2017

Keywords

cluster compounds
hydrogen bonds
hydrogen peroxides
structure elucidation
supramolecular chemistry

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry

Access to Document

10.1002/anie.201709699

Cite this

@article{722e92590ba8471b9fd05ee8da1e63d5,

title = "Hydrogen Peroxide Insular Dodecameric and Pentameric Clusters in Peroxosolvate Structures",

abstract = "Peroxosolvates of 2-aminonicotinic acid (I) and lidocaine N-oxide (II) including the largest insular hydrogen peroxide clusters were isolated and their crystal structures were determined by single-crystal X-ray diffraction. An unprecedented dodecameric hydrogen peroxide insular cluster was found in I. An unusual cross-like pentameric cluster was observed in the structure of II. The topology of the (H2O2)12 assembly was never observed for small-molecule clusters. In I and II new double and triple cross-orientational disorders of H2O2 were found. Cluster II is the first example of a peroxosolvate crystal structure containing H2O2 molecules with a homoleptic hydrogen peroxide environment. In II, a hydrogen bond between an H2O2 molecule and a peptide group -CONH⋅⋅⋅O2H2 was observed for the first time.",

keywords = "cluster compounds, hydrogen bonds, hydrogen peroxides, structure elucidation, supramolecular chemistry",

author = "Grishanov, \{Dmitry A.\} and Navasardyan, \{Mger A.\} and Medvedev, \{Alexander G.\} and Ovadia Lev and Prikhodchenko, \{Petr V.\} and Churakov, \{Andrei V.\}",

note = "Publisher Copyright: {\textcopyright} 2017 Wiley-VCH Verlag GmbH \& Co. KGaA, Weinheim",

year = "2017",

month = nov,

day = "27",

doi = "10.1002/anie.201709699",

language = "الإنجليزيّة",

volume = "56",

pages = "15241--15245",

journal = "Angewandte Chemie - International Edition",

issn = "1433-7851",

publisher = "John Wiley and Sons Ltd",

number = "48",

}

TY - JOUR

T1 - Hydrogen Peroxide Insular Dodecameric and Pentameric Clusters in Peroxosolvate Structures

AU - Grishanov, Dmitry A.

AU - Navasardyan, Mger A.

AU - Medvedev, Alexander G.

AU - Lev, Ovadia

AU - Prikhodchenko, Petr V.

AU - Churakov, Andrei V.

PY - 2017/11/27

Y1 - 2017/11/27

N2 - Peroxosolvates of 2-aminonicotinic acid (I) and lidocaine N-oxide (II) including the largest insular hydrogen peroxide clusters were isolated and their crystal structures were determined by single-crystal X-ray diffraction. An unprecedented dodecameric hydrogen peroxide insular cluster was found in I. An unusual cross-like pentameric cluster was observed in the structure of II. The topology of the (H2O2)12 assembly was never observed for small-molecule clusters. In I and II new double and triple cross-orientational disorders of H2O2 were found. Cluster II is the first example of a peroxosolvate crystal structure containing H2O2 molecules with a homoleptic hydrogen peroxide environment. In II, a hydrogen bond between an H2O2 molecule and a peptide group -CONH⋅⋅⋅O2H2 was observed for the first time.

AB - Peroxosolvates of 2-aminonicotinic acid (I) and lidocaine N-oxide (II) including the largest insular hydrogen peroxide clusters were isolated and their crystal structures were determined by single-crystal X-ray diffraction. An unprecedented dodecameric hydrogen peroxide insular cluster was found in I. An unusual cross-like pentameric cluster was observed in the structure of II. The topology of the (H2O2)12 assembly was never observed for small-molecule clusters. In I and II new double and triple cross-orientational disorders of H2O2 were found. Cluster II is the first example of a peroxosolvate crystal structure containing H2O2 molecules with a homoleptic hydrogen peroxide environment. In II, a hydrogen bond between an H2O2 molecule and a peptide group -CONH⋅⋅⋅O2H2 was observed for the first time.

KW - cluster compounds

KW - hydrogen bonds

KW - hydrogen peroxides

KW - structure elucidation

KW - supramolecular chemistry

UR - http://www.scopus.com/inward/record.url?scp=85031671211&partnerID=8YFLogxK

U2 - 10.1002/anie.201709699

DO - 10.1002/anie.201709699

M3 - مقالة

C2 - 28991407

SN - 1433-7851

VL - 56

SP - 15241

EP - 15245

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 48

ER -

Hydrogen Peroxide Insular Dodecameric and Pentameric Clusters in Peroxosolvate Structures

Abstract

Keywords

All Science Journal Classification (ASJC) codes

Access to Document

Other files and links

Fingerprint

Cite this