Guests on different internal capsule sites exchange with each other and with the outside

Olga Petina; Dieter Rehder; Erhard T.K. Haupt; Alina Grego; Ira A. Weinstock; Alice Merca; Hartmut Bögge; Julia Szakács; Achim Müller

doi:https://doi.org/10.1002/anie.201005596

Guests on different internal capsule sites exchange with each other and with the outside

Olga Petina, Dieter Rehder, Erhard T.K. Haupt, Alina Grego, Ira A. Weinstock, Alice Merca, Hartmut Bögge, Julia Szakács, Achim Müller

Department of Chemistry

Ben-Gurion University of the Negev

Research output: Contribution to journal › Article › peer-review

Abstract

In and out: Compartmentalization in a porous polyoxometalate capsule (see structure, red and blue polyhedra) allows acetate ions (green/red or orange/red), coordinated to different internal sites, to exchange not only with each other (yellow double arrow) but also with those outside in bulk aqueous solution.

Original language	American English
Pages (from-to)	410-414
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	50
Issue number	2
DOIs	https://doi.org/10.1002/anie.201005596
State	Published - 10 Jan 2011

Keywords

NMR spectroscopy
capsules
equilibria
guest exchange
polyoxometalates

All Science Journal Classification (ASJC) codes

General Chemistry
Catalysis

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https://doi.org/10.1002/anie.201005596

Cite this

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AU - Merca, Alice

AU - Bögge, Hartmut

AU - Szakács, Julia

AU - Müller, Achim

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KW - equilibria

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Guests on different internal capsule sites exchange with each other and with the outside

Abstract

Keywords

All Science Journal Classification (ASJC) codes

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