Gradient isotactic multiblock polylactides from aluminum complexes of chiral salalen ligands

Alessia Pilone; Konstantin Press; Israel Goldberg; Moshe Kol; Mina Mazzeo; Marina Lamberti

doi:10.1021/ja412798x

Gradient isotactic multiblock polylactides from aluminum complexes of chiral salalen ligands

Alessia Pilone, Konstantin Press, Israel Goldberg, Moshe Kol, Mina Mazzeo, Marina Lamberti

School of Chemistry

Tel Aviv University

Research output: Contribution to journal › Article › peer-review

Abstract

Aluminum complexes of enantiomerically pure aminomethylpyrrolidine-based salalen ligands and their application in the stereoselective polymerization of lactide are described. Poly(lactic acid) featuring the new gradient isotactic multiblock microstructure was synthesized by isoselective catalysts, which operate by a combination of enantiomorphic-site and chain-end control mechanisms.

Original language	English
Pages (from-to)	2940-2943
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	136
Issue number	8
DOIs	https://doi.org/10.1021/ja412798x
State	Published - 26 Feb 2014

All Science Journal Classification (ASJC) codes

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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10.1021/ja412798x

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title = "Gradient isotactic multiblock polylactides from aluminum complexes of chiral salalen ligands",

abstract = "Aluminum complexes of enantiomerically pure aminomethylpyrrolidine-based salalen ligands and their application in the stereoselective polymerization of lactide are described. Poly(lactic acid) featuring the new gradient isotactic multiblock microstructure was synthesized by isoselective catalysts, which operate by a combination of enantiomorphic-site and chain-end control mechanisms.",

author = "Alessia Pilone and Konstantin Press and Israel Goldberg and Moshe Kol and Mina Mazzeo and Marina Lamberti",

year = "2014",

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day = "26",

doi = "10.1021/ja412798x",

language = "الإنجليزيّة",

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T1 - Gradient isotactic multiblock polylactides from aluminum complexes of chiral salalen ligands

AU - Pilone, Alessia

AU - Press, Konstantin

AU - Goldberg, Israel

AU - Kol, Moshe

AU - Mazzeo, Mina

AU - Lamberti, Marina

PY - 2014/2/26

Y1 - 2014/2/26

N2 - Aluminum complexes of enantiomerically pure aminomethylpyrrolidine-based salalen ligands and their application in the stereoselective polymerization of lactide are described. Poly(lactic acid) featuring the new gradient isotactic multiblock microstructure was synthesized by isoselective catalysts, which operate by a combination of enantiomorphic-site and chain-end control mechanisms.

AB - Aluminum complexes of enantiomerically pure aminomethylpyrrolidine-based salalen ligands and their application in the stereoselective polymerization of lactide are described. Poly(lactic acid) featuring the new gradient isotactic multiblock microstructure was synthesized by isoselective catalysts, which operate by a combination of enantiomorphic-site and chain-end control mechanisms.

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U2 - 10.1021/ja412798x

DO - 10.1021/ja412798x

M3 - مقالة

SN - 0002-7863

VL - 136

SP - 2940

EP - 2943

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 8

ER -

Gradient isotactic multiblock polylactides from aluminum complexes of chiral salalen ligands

Abstract

All Science Journal Classification (ASJC) codes

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